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However, the commonly used Pt and Pd catalysts suffer from undesirable activity and fast deactivation. Herein, we designed a AuPtPdRh medium\u2010entropy aerogel (MEA) with multi\u2010site synergies, coupled with dynamic potential modulation strategy, to achieve efficient GA synthesis. The AuPtPdRh MEA reduces the overall energy barrier through a potential relay\u2010type catalytic mechanism across distinct active sites. The potential sweep\u2010step hybrid electrolysis (PS\u2010SHE) modulation strategy establishes a \u201cprogressive pre\u2010enrichment\u2014pulsed cleaning\u2010regeneration\u201d cycle, which enhances catalytic activity and stability. This system achieves 98% Faradaic efficiency (FE) for GA (FE\n                    <jats:sub>GA<\/jats:sub>\n                    ), as well as an GA production rate (PR\n                    <jats:sub>GA<\/jats:sub>\n                    ) of up to 8.82\u00a0mmol cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Additionally, it can maintain stable operation for 500\u00a0h at an ampere\u2010level current density (0.25 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) in a membrane\u2010free flow cell. The universality of this approach is further demonstrated for methanol, ethanol, and propanol electrooxidation, providing a versatile platform for biomass valorization.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521577","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T21:13:48Z","timestamp":1773004428000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Synergistic OH\n                    <sup>\u2212<\/sup>\n                    \/H\n                    <sub>2<\/sub>\n                    O Engineering and Dynamic Potential Modulation for Efficient Upcycling of PET Waste to Glycolic Acid Using H\n                    <sub>2<\/sub>\n                    O as the Oxygen Source"],"prefix":"10.1002","volume":"65","author":[{"given":"Taoyuan","family":"Tian","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongjie","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongjing","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou P.R. 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