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Here, we report an acid\u2010programmed generating approach, in which reaction acidity simultaneously modulates ligand protonation and the nucleation barrier, thereby generating coordination, ionic, and all\u2010in\u2010one copper(I) chloride architectures by tuning reaction acidity and affording six new compounds with emissions spanning 520\u2013625\u00a0nm. Among these, the AIO compound\n                    <jats:bold>3<\/jats:bold>\n                    A\u20101H[CuCl\n                    <jats:sub>2<\/jats:sub>\n                    ] (A\u00a0=\u00a04\u2010(aminomethyl)pyridine, 4AMP) exhibits a record\u2010high photoluminescence quantum yield (PLQY) of 99%, setting a new benchmark for AIO Cu(I)\u2010based emitters. Temperature\u2010dependent photoluminescence and time\u2010resolved spectroscopy reveal that the ultrahigh PLQY originates from enhanced lattice rigidity and a triplet phosphorescence pathway. Solubility and thin film fabrication demonstrate excellent processability, while long\u2010term stability stands in stark contrast to the notorious instability of conventional Cu(I) halides. Moreover, mixing compounds yields broad\u2010range white\u2010light emission, underscoring the potential of materials for tunable and high\u2010efficiency solid\u2010state lighting. This study establishes acid\u2010driven structural integration as a general strategy for constructing functional copper(I) halide compounds, laying the foundation for stable, solution\u2010processable, and high\u2010performance optoelectronic materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521806","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T14:23:01Z","timestamp":1767882181000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Acid\u2010Programmed Generation of Coordination, Ionic, and All\u2010In\u2010One Cu(I) Chloride Architectures with Highly Efficient Luminescence"],"prefix":"10.1002","volume":"65","author":[{"given":"Qinglin","family":"Meng","sequence":"first","affiliation":[{"name":"Institute of New Energy Technology Jinan University  Guangzhou 510632 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