{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T03:28:27Z","timestamp":1783740507604,"version":"3.55.0"},"reference-count":48,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2025,12,21]],"date-time":"2025-12-21T00:00:00Z","timestamp":1766275200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,21]],"date-time":"2025-12-21T00:00:00Z","timestamp":1766275200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22136002 22172064"],"award-info":[{"award-number":["22136002 22172064"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Solar\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction suffers from severe hole accumulation and inefficient electron utilization due to the sluggish kinetics of H\n                    <jats:sub>2<\/jats:sub>\n                    O oxidation to O\n                    <jats:sub>2<\/jats:sub>\n                    , thereby impeding the multi\u2010electron C\u2500C coupling process. This results in poor catalytic activity of C\n                    <jats:sub>2<\/jats:sub>\n                    products. Herein, we have constructed a conjugated stacked thiophene\u2010based supramolecular catalyst with extensive \u03c0\u2010electron delocalization by introducing a benzene ring. This effectively promotes the oxidation of H\n                    <jats:sub>2<\/jats:sub>\n                    O to H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , significantly accelerating hole consumption and thereby enhancing the electron reduction reaction of CO\n                    <jats:sub>2<\/jats:sub>\n                    at the metal center. Under illumination, the C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    production rate reached 101.1 \u00b5mol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with an electron selectivity as high as 98%. Compared to existing advanced systems, this represents an order\u2010of\u2010magnitude breakthrough in activity for C\n                    <jats:sub>2<\/jats:sub>\n                    product synthesis. Research indicates that the enrichment of \u03c0 electrons on the benzene ring of the catalyst can stabilize the H\n                    <jats:sub>2<\/jats:sub>\n                    O oxidation intermediate *OH, consuming a significant number of holes to form H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    . This process enhances the separation and migration of photo\u2010generated electrons at the active center and promoting the *CO\u2010bridged C\u2500C coupling. This significantly increases the ability to reduce CO\n                    <jats:sub>2<\/jats:sub>\n                    to C\n                    <jats:sub>2<\/jats:sub>\n                    products. This work provides new insights into the economic viability of photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    under pure H\n                    <jats:sub>2<\/jats:sub>\n                    O conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521909","type":"journal-article","created":{"date-parts":[[2025,12,22]],"date-time":"2025-12-22T05:42:47Z","timestamp":1766382167000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Activity Breakthrough in CO\n                    <sub>2<\/sub>\n                    Photoreduction to C\n                    <sub>2<\/sub>\n                    H\n                    <sub>6<\/sub>\n                    via Accelerated Electron Accumulation from H\n                    <sub>2<\/sub>\n                    O Photooxidation to H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"65","author":[{"given":"Tingyu","family":"Yang","sequence":"first","affiliation":[{"name":"International Joint Research Center for Photo\u2010responsive Molecules and Materials School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Sun","sequence":"additional","affiliation":[{"name":"International Joint Research Center for Photo\u2010responsive Molecules and Materials School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2999-1325","authenticated-orcid":false,"given":"Yuming","family":"Dong","sequence":"additional","affiliation":[{"name":"International Joint Research Center for Photo\u2010responsive Molecules and Materials School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Zhang","sequence":"additional","affiliation":[{"name":"International Joint Research Center for Photo\u2010responsive Molecules and Materials School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinxin","family":"Jiang","sequence":"additional","affiliation":[{"name":"International Joint Research Center for Photo\u2010responsive Molecules and Materials School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongfa","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,21]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406223"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313392"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001023\u20101"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10351"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00432"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057742\u20105"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216232"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c10023"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.08.018"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319177"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00564"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309624"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201904433"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010023\u201001214\u20102"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00880"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14590"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06820"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06660"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422348"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12155"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315599"},{"key":"e_1_2_7_22_1","author":"Wang G.","year":"2022","journal-title":"Angew. 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