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Through molecular engineering integrating chiral\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010terminal groups with electronically tunable azobenzene (Azo) side chains, we demonstrate that in kinetically trapped aggregates of side chain Azo polymers, the dipole moment of the chromophore, modulated by terminal electron\u2010donating (Donor, D) or withdrawing (Acceptor, A) substituents, dictates the absolute inversion of the resulting supramolecular helix. The substituent\u2010dependent dipole reorientation cascades into long\u2010range helical reorganization via \u03c0\u2010\u03c0 and van der Waals cooperativity, ultimately governing whether chirality transfer follows thermodynamic preference, undergoes inversion, or exhibits multiplexed behavior. This electronically driven chirality inversion transcends classical steric models and establishes a transformative framework for designing adaptive chiral materials with programmable handedness, offering promising applications in photonic circuits, enantioselective nanosensors, and bioinspired metamaterials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202521913","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T07:55:01Z","timestamp":1770364501000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Donor\u2013Acceptor Engineering Enables Kinetic Control of Chirality Transfer in Side Chain Polymers"],"prefix":"10.1002","volume":"65","author":[{"given":"Tengfei","family":"Miao","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory For Chemistry of Low\u2010Dimensional Materials School of Chemistry and Chemical Engineering Huaiyin Normal University  Huaian Jiangsu 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