{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T19:06:33Z","timestamp":1789671993904,"version":"4.0.1"},"reference-count":46,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T00:00:00Z","timestamp":1778198400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T00:00:00Z","timestamp":1778198400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003398","name":"Shanxi Scholarship Council of China","doi-asserted-by":"publisher","award":["2024\u2010005"],"award-info":[{"award-number":["2024\u2010005"]}],"id":[{"id":"10.13039\/501100003398","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,6,15]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The rising global energy demand, driven by population and economic growth, continues to be met largely by fossil fuels. Consequently, atmospheric CO\n                    <jats:sub>2<\/jats:sub>\n                    concentration has increased from \u223c280\u00a0ppm in the pre\u2010industrial era to over 430\u00a0ppm today, motivating integrated capture\u2010and\u2010conversion strategies that valorize CO\n                    <jats:sub>2<\/jats:sub>\n                    as a feedstock. Amines are widely employed for post\u2010combustion CO\n                    <jats:sub>2<\/jats:sub>\n                    capture due to their low cost, rapid kinetics, and reversible carbamate formation. These amine\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    adducts can be hydrogenated to formamides and subsequently to methanol under mild conditions (&lt;150\u00b0C), regenerating the amine. However, selective C\u2500N bond cleavage during the formamide hydrogenation for efficient release of methanol without sorbent deactivation remains a key challenge. Here, we demonstrate that 1 wt% Pt supported on TiO\n                    <jats:sub>2<\/jats:sub>\n                    (commercial P25) catalyzes the conversion of 4\u2010formylmorpholine to methanol with up to 62% yield and 95% selectivity at 150\u00b0C. In situ characterizations and DFT computations reveal that strong interaction between dispersed Pt and the support promotes selective C\u2500N hydrogenolysis. The catalyst also exhibits excellent stability. These findings establish a robust heterogeneous platform for combined CO\n                    <jats:sub>2<\/jats:sub>\n                    capture and methanol synthesis, highlighting the critical role of support\u2010induced electronic effects in controlling bond scission.\n                  <\/jats:p>","DOI":"10.1002\/anie.202522476","type":"journal-article","created":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T13:26:16Z","timestamp":1778246776000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Selective Hydrogenation of Formamide to Methanol Over Supported Platinum Catalysts"],"prefix":"10.1002","volume":"65","author":[{"given":"Xuetao","family":"Qin","sequence":"first","affiliation":[{"name":"Leibniz\u2010Institut F\u00fcr Katalyse e.V.  Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"XinXin","family":"Tian","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institut F\u00fcr Katalyse e.V.  Rostock Germany"},{"name":"Institute of Molecular Science Shanxi University  Taiyuan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shou","family":"Qiu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Engineering New Cornerstone Science Laboratory College of Chemistry and Molecular Engineering Peking University  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han","family":"Yan","sequence":"additional","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes Department of Chemical Physics University of Science and Technology of China  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haijun","family":"Jiao","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institut F\u00fcr Katalyse e.V.  Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Henrik","family":"Junge","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institut F\u00fcr Katalyse e.V.  Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5709-0965","authenticated-orcid":false,"given":"Matthias","family":"Beller","sequence":"additional","affiliation":[{"name":"Leibniz\u2010Institut F\u00fcr Katalyse e.V.  Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,8]]},"reference":[{"key":"e_1_2_7_2_1","unstructured":"D. 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