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Here, we establish a direct link between interfacial curvature and confined water behavior using an archaeal\u2010inspired phytantriol\u2010water lipidic mesophase platform. By systematically tuning curvature across lamellar, double\u2010gyroid cubic, and reverse micellar phases, and integrating structural, thermodynamic, and ultrafast spectroscopies, we show that geometry controls the dimensionality and mobility of the hydrogen\u2010bond network. Planar interfaces enforce 2D networks that slow down interfacial water through spatial constrain, whereas curved bicontinuous and micellar topologies promote 3D networks with accelerated reorientation. These findings reveal a geometric principle for governing water dynamics in soft nanoconfinement, providing molecular level design rules for confined transport and reactivity in membranes and functional materials.<\/jats:p>","DOI":"10.1002\/anie.202522757","type":"journal-article","created":{"date-parts":[[2026,1,10]],"date-time":"2026-01-10T13:50:21Z","timestamp":1768053021000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Geometry Controls Confined Water Dynamics in Lipidic Mesophases"],"prefix":"10.1002","volume":"65","author":[{"given":"Sara","family":"Catalini","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Basel  Basel Switzerland"},{"name":"Department of Chemistry \u201cUgo Schiff\u201d University of Florence  Florence Italy"},{"name":"European Laboratory for Non\u2010Linear Spectroscopy  Florence 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