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However, the competitive adsorption of proton at low overpotential limits CO production by inhibiting the activation and hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    to form the key intermediates,\n                    <jats:sup>*<\/jats:sup>\n                    COOH. To address this challenge, we developed a Cu\u2500Cd alloy catalyst, which optimizes the proton\u2010coupled electron transfer (PCET) pathway through a synergistic regulation between dual Cu and Cd active sites. In situ spectroscopy and theoretical calculations reveal that Cd incorporation enhances\n                    <jats:sup>*<\/jats:sup>\n                    CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and lowers the energy barrier for\n                    <jats:sup>*<\/jats:sup>\n                    COOH formation. By proving direct electrochemical hydrogenation, our catalyst achieved a remarkable CO Faradaic efficiency (FE) of 98.6% at\u00a0\u22121.12\u00a0V versus RHE, and operated for over 250\u00a0h at a total current of 0.4\u00a0A under a voltage of 2.55\u00a0V in a proton exchange membrane electrode assembly. This research presents a powerful new insight for high\u2010performance acidic CO\n                    <jats:sub>2<\/jats:sub>\n                    electrolysis in proton\u2010abundant electrolyte environments.\n                  <\/jats:p>","DOI":"10.1002\/anie.202522764","type":"journal-article","created":{"date-parts":[[2025,12,17]],"date-time":"2025-12-17T11:46:11Z","timestamp":1765971971000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Differential Adsorption on Synergistic Cu\u2500Cd Sites Enables Direct Hydrogenation in Acidic CO\n                    <sub>2<\/sub>\n                    Electroreduction"],"prefix":"10.1002","volume":"65","author":[{"given":"Liyuan","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  1037 Luoyu Rd Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lebin","family":"Cai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  1037 Luoyu Rd Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wensheng","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  1037 Luoyu Rd Wuhan 430074 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School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  1037 Luoyu Rd Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ho Seok","family":"Park","sequence":"additional","affiliation":[{"name":"Center for Next\u2010Generation Energy Materials, School of Chemical Engineering Sungkyunkwan University (SKKU)  2066, Seobu\u2010ro, Jangan\u2010gu Suwon Gyeonggi\u2010do 16419 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Song","sequence":"additional","affiliation":[{"name":"Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201800 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2054-908X","authenticated-orcid":false,"given":"Bao Yu","family":"Xia","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced 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