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However, conventional solid or liquid additives face inherent limitations such as high production costs, chemical instability, and inefficient interfacial passivation, restricting their practical application. Here, we propose an electrolyte engineering strategy that makes sustainable use of sulfur dioxide (SO\n                    <jats:sub>2<\/jats:sub>\n                    ), an industrial waste\u2010derived gas, as a dual\u2010functional gaseous additive. Owing to its ultrahigh reduction potential (2.6\u00a0V versus Li\n                    <jats:sup>+<\/jats:sup>\n                    \/Li), which exceeds that of most known additives, and a low oxidation potential, SO\n                    <jats:sub>2<\/jats:sub>\n                    promotes the in situ formation of sulfur\u2010containing interphases on both electrodes through preferential electrochemical reactions, thereby effectively suppressing parasitic electrolyte decomposition. SO\n                    <jats:sub>2<\/jats:sub>\n                    enables 4.4\u00a0V\u2010class AG || NCM613 pouch cells to achieve exceptional cyclability exceeding 800 cycles with 88.2% capacity retention, along with outstanding temperature tolerance from \u221230\u00a0\u00b0C to 45\u00a0\u00b0C. This strategy also demonstrates universal applicability, yielding a long life of 800 cycles for Ah\u2010level 4.3\u00a0V\u2010class Si\/C || NCM811 pouch cells. Furthermore, this approach alleviates electrolyte discoloration, extending shelf life while reducing cost and energy consumption. This work establishes a sustainable circular economy model by valorizing industrial exhaust into high\u2010value battery components, bridging environmental stewardship with next\u2010generation energy storage innovation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523079","type":"journal-article","created":{"date-parts":[[2026,1,17]],"date-time":"2026-01-17T06:27:31Z","timestamp":1768631251000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Gaseous SO\n                    <sub>2<\/sub>\n                    Additive for High\u2010Energy\u2010Density Li\u2010Ion Battery"],"prefix":"10.1002","volume":"65","author":[{"given":"Xuequan","family":"Zhu","sequence":"first","affiliation":[{"name":"National Engineering Laboratory for Green Chemical Productions of Alcohols\u2010Ethers\u2010Esters State Key Laboratory of Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 P.R. 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