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However, the development of organic ML systems has long been limited by the trade\u2010off among brightness, sensitivity, and mechanical durability. Here, we present a supramolecular assembly design that overcomes this trade\u2010off by leveraging directional fluorine interactions, i.e., well\u2010defined C\u2500H\u00b7\u00b7\u00b7F\u2500C hydrogen\u2010bonds and the rarely reported\n                    <jats:italic>L<\/jats:italic>\n                    \u2010geometry C\u2500F\u00b7\u00b7\u00b7F\u2500C contacts. The resulting supramolecular network stabilizes favorable molecular packing against mechanical damage while preserving optimal crystallinity, leading to bright and durable ML emission even during continuous mechanical grinding. Systematic structure\u2013property analysis has successfully revealed the key design criteria for high\u2010performance ML. We also establish a universal supramolecular platform that enables efficient F\u00f6rster resonance energy transfer from the ML host to the ML\u2010inactive luminophores across the visible spectrum (green, yellow, and red). Furthermore, the fabricated prototype supramolecular ML stress sensors exhibit remarkable sensitivity, with naked\u2010eye\u2010detectable ML at an ultralow impact force of 0.05\u00a0N. This work has put forward that fluorine\u2010driven supramolecular assembly is a robust and versatile design strategy for advanced organic ML materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523121","type":"journal-article","created":{"date-parts":[[2025,12,13]],"date-time":"2025-12-13T04:03:17Z","timestamp":1765598597000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Supramolecular Mechanoluminescence via Fluorine Interactions"],"prefix":"10.1002","volume":"65","author":[{"given":"Weiguo","family":"Qiao","sequence":"first","affiliation":[{"name":"Key Laboratory for Material Chemistry of Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"},{"name":"School of Chemistry and Chemical Engineering Henan University of 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