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Key to the formation of this monomeric species is the steric protection offered by the supporting phosphaalkenyl ligand which hinders aggregation. The title compound can be accessed from the reaction of (InTer)\n                    <jats:sub>2<\/jats:sub>\n                    with the phosphaalkyne AdC\u2261P in an unusual redox\u2010neutral transformation in which the In\u2500C bond of the (InTer)\n                    <jats:sub>2<\/jats:sub>\n                    precursor, known to dissociate in solution, adds across the C\u2261P triple bond of the phosphaalkyne. This insertion reaction is reversible, as shown by the reaction of In[C(Ad)\u2550PTer] with B(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    , which affords [TerInB(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ] accompanied by extrusion of AdC\u2261P. In contrast, the lighter analogue (GaTer)\n                    <jats:sub>2<\/jats:sub>\n                    promotes the dimerization of the AdC\u2261P fragment resulting in the formation of the cluster (GaTer)\n                    <jats:sub>2<\/jats:sub>\n                    (AdCP)\n                    <jats:sub>2<\/jats:sub>\n                    . The formal oxidation state of In[C(Ad) = PTer] was probed by reaction with methyl\u2010iodide which affords the indium(III) compound In(Me)I[C(Ad) = PTer] in a formal single\u2010site oxidative\u2010addition reaction at indium.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523125","type":"journal-article","created":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T05:25:22Z","timestamp":1768541122000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Crystalline Mono\u2010Coordinate Indium(I)\u2010Phosphaalkenyl"],"prefix":"10.1002","volume":"65","author":[{"given":"\u00c1lvaro","family":"Garc\u00eda\u2010Romero","sequence":"first","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maren","family":"Pink","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Israel","family":"Fern\u00e1ndez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Org\u00e1nica and Centro de Innovaci\u00f3n en Qu\u00edmica Avanzada (ORFEO\u2010CINQA), Universidad Complutense de Madrid Facultad de Ciencias Qu\u00edmicas  Madrid 28040 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7311-1663","authenticated-orcid":false,"given":"Jose M.","family":"Goicoechea","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indiana University  800 East Kirkwood Ave. Bloomington Indiana 47405 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