{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T16:54:27Z","timestamp":1790182467062,"version":"4.1.0"},"reference-count":72,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,1]],"date-time":"2026-03-01T00:00:00Z","timestamp":1772323200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22472153"],"award-info":[{"award-number":["22472153"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22241801"],"award-info":[{"award-number":["22241801"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22032005"],"award-info":[{"award-number":["22032005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22022202"],"award-info":[{"award-number":["22022202"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22402190"],"award-info":[{"award-number":["22402190"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,4,13]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Alkaline desilication is commonly used to create hierarchical pores in zeolites but is often limited by dealumination and surface passivation, as leached aluminum (Al) species redeposit with silanol groups, leaving the framework Si\/Al ratio largely unchanged. Here, we reveal a self\u2010correcting Al migration mechanism in zeolites (SSZ\u201013, SSZ\u201039, Y, and AFX) only containing 4\u2010membered ring(4R)\u2013organized double\u20106\u2010membered ring(D\u20106R) secondary building units (SBUs). During alkaline treatment, leached Al species dynamically reincorporate into the framework, mitigating passivation and enabling continuous desilication accompanied by significant Si\/Al reduction. This process produces Al\u2010pair\u2010enriched hierarchical SSZ\u201039 with framework Si\/Al ratio as low as 2\u2014previously unattainable through conventional synthesis. Using SSZ\u201013 as a model, we identify a two\u2010stage evolution: rapid desilication forming silica\u2013alumina fragments, followed by Al migration that transforms isolated Al into paired Al species stabilized within SBUs under strong alkalinity. The resulting Al\u2010rich SSZ\u201013\/SSZ\u201039 zeolites and derivatives exhibit enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and improved catalytic activity in Wacker oxidation and methanol\u2010to\u2010olefin reactions. This SBUs\u2010directed Al redistribution creates high\u2010silica hierarchical variants and establishes a general strategy to control porosity, Al distribution, and multifunctionality in zeolites for adsorption, ion exchange, and catalysis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523357","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:11:32Z","timestamp":1773007892000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Engineering Al\u2010Pair\u2010Enriched Hierarchical Zeolites via D\u20106R SBU\u2010Directed Aluminum Reorganization During Desilication"],"prefix":"10.1002","volume":"65","author":[{"given":"Jie","family":"Yu","sequence":"first","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory of Advanced Catalysis and Adsorption Materials Institute of Physical Chemistry Zhejiang Normal University  Jinhua China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huihui","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxia","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory of Advanced Catalysis and Adsorption Materials Institute of Physical Chemistry Zhejiang Normal University  Jinhua China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tongrui","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhao","family":"Cui","sequence":"additional","affiliation":[{"name":"Division of Energy Research Resources Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shanfan","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quancai","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory of Advanced Catalysis and Adsorption Materials Institute of Physical Chemistry Zhejiang Normal University  Jinhua China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiujie","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenchao","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory of Advanced Catalysis and Adsorption Materials Institute of Physical Chemistry Zhejiang Normal University  Jinhua China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qihua","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory of Advanced Catalysis and Adsorption Materials Institute of Physical Chemistry Zhejiang Normal University  Jinhua China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4722-8371","authenticated-orcid":false,"given":"Shutao","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"University of Chinese Academy of Sciences  Beijing P.R. China"},{"name":"Liaoning Binhai Laboratory  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,1]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010021\u201000347\u20103"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470822371.ch2"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00274"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00626K"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature06552"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00016"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr4001513"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.4c00076"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202004690"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706566"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00520E"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201300345"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14741"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cy00150g"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416564"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2014.02.040"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.04.023"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2023.112740"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2010.03.017"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00798A"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CS00319A"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00738"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp952189k"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.5c00094"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002416"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2012.03.045"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2009.08.016"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abo3093"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2005.02.016"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004\u2010018\u20100066\u20103"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm2032515"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.3c06292"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b11294"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b04554"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b00181"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01273"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal10010123"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c00856"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0141\u20103910(02)00378\u20106"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c03036"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07969"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac155"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00590"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409635"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/0926\u20102040(95)01201\u2010X"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202002181"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp060505x"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1201\/9780203911167.ch3"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2023.112614"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201601623"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2022.112184"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b04052"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507223"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2004.02.016"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg100289p"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2012.08.014"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10528"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a008"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b01577"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00404"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja210580b"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal11111355"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010020\u201000533\u20106"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201004748\u2010x"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aam9035"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC08835K"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201014982\u2010x"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC09719C"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004360"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp970900a"},{"key":"e_1_2_7_72_1","unstructured":"C.Baerlocher D.Brouwer B.Marler andL. B.McCusker Database of Zeolite Structures https:\/\/www.iza\u2010structure.org\/databases\/."},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1387\u20101811(98)00271\u20106"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523357","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202523357","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523357","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,15]],"date-time":"2026-04-15T07:27:25Z","timestamp":1776238045000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202523357"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3,1]]},"references-count":72,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2026,4,13]]}},"alternative-id":["10.1002\/anie.202523357"],"URL":"https:\/\/doi.org\/10.1002\/anie.202523357","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,3,1]]},"assertion":[{"value":"2025-10-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e23357"}}