{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T08:20:46Z","timestamp":1791534046942,"version":"4.3.4"},"reference-count":58,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92472125"],"award-info":[{"award-number":["92472125"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22179124"],"award-info":[{"award-number":["22179124"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,3,16]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to ethanol faces a fundamental challenge: competing ethylene formation through shared C\n                    <jats:sub>2<\/jats:sub>\n                    intermediates. While previous studies focused on modifying catalyst electronic structures or increasing *CO coverage, the critical role of competitive hydrogenation pathways remains unexplored. Here, we demonstrate that the selectivity between ethanol and ethylene is governed by the balance between Langmuir\u2013Hinshelwood (surface *H) and Eley\u2013Rideal (solvent H) hydrogenation mechanisms. Through hierarchically assembled BPEI\/PT interfaces, we dynamically modulate this balance by reconstructing interfacial hydrogen\u2010bond networks without altering catalyst electronic properties. In situ Raman spectroscopy captures enhanced *OCHCH\n                    <jats:sub>2<\/jats:sub>\n                    \/*OCHCH\n                    <jats:sub>3<\/jats:sub>\n                    intermediates, directly correlating ethanol selectivity with suppressed ER pathway. Combined experimental and theoretical studies establish quantitative relationships between hydrogen\u2010bond strength and pathway selectivity. This strategy achieves 38.7% ethanol Faradaic efficiency (FE) at 900\u00a0mA cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    on CuO\u2010derived catalysts (116% improvement) and 53% at 800\u00a0mA cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    on CuAg systems\u2014among the highest reported efficiencies. Our findings reveal that controlling competitive hydrogenation pathways through interfacial engineering provides an independent parameter for steering CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction selectivity.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523475","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T05:22:36Z","timestamp":1770355356000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Tailoring Hydrogenation Pathway to Redirect CO\n                    <sub>2<\/sub>\n                    Electroreduction From Ethylene to Ethanol"],"prefix":"10.1002","volume":"65","author":[{"given":"Zihong","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiasen","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dazhuang","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuefei","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuangzhuang","family":"Cui","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Digen","family":"Ruan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuan","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajia","family":"Fan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiacheng","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing\u2010Qing","family":"Xiong","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2025-7554","authenticated-orcid":false,"given":"Xiaodi","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,5]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010025\u201001359\u2010w"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001695\u20104"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010025\u201001859\u2010z"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051928\u2010z"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061132\u20102"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2024.110437"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2218987120"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201039351\u20102"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001633\u20104"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000880\u20106"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049247\u20104"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13384"},{"key":"e_1_2_8_14_1","article-title":"Switching CO2 Electroreduction Pathways Between Ethylene and Ethanol via Tuning Microenvironment of the Coating on Copper Nanofibers","volume":"64","author":"Han B.","year":"2024","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410659"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201031427\u20109"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010020\u20100450\u20100"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010019\u20101782\u20102"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0607-8"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06846"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010024\u201001721\u20108"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c03797"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001162\u2010z"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418459"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504515"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05880"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317512"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0383-7"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE00900H"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012631"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja500328k"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412754"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00539A"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407992"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14299"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201035912\u20107"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201050269\u20101"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c03423"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2015.06.050"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-021-04068-z"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100296\u20108"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27372-8"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5SC00274E"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302096"},{"key":"e_1_2_8_45_1","first-page":"13306","article-title":"Elucidating the Role of Single\u2010Atom Pd for Electrocatalytic Hydrodechlorination","volume":"55","author":"Huang D.","year":"2021","journal-title":"Environmental Science & Technology"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06697"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201017231\u20103"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c03850"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05857"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309351"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000967\u20107"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01478"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09255"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03830"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11359"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201036926\u2010x"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.2c01857"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1612106114"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-821978-2.00076-3"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523475","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202523475","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523475","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,16]],"date-time":"2026-03-16T15:10:39Z","timestamp":1773673839000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202523475"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,5]]},"references-count":58,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2026,3,16]]}},"alternative-id":["10.1002\/anie.202523475"],"URL":"https:\/\/doi.org\/10.1002\/anie.202523475","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,5]]},"assertion":[{"value":"2025-10-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e23475"}}