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Herein, we developed a cost\u2010effective and scalable facile immersion treatment to deposit a hydrophobic 1,3\u2010Di(o\u2010tolyl)thiourea (DTH) layer with nanoscale thickness (\u2264 14\u00a0nm). This approach yields an ultra\u2010low DTH loading (5.37 \u00d7 10\n                    <jats:sup>\u221213<\/jats:sup>\n                    \u00a0M) and exceptional cost efficiency (1.43 \u00d7 10\n                    <jats:sup>\u22127<\/jats:sup>\n                    USD Ah\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), surpassing conventional water\u2010miscible organic additives and biomass\u2010derived counterparts by orders of magnitude. The hydrophobic DTH layer optimizes Zn electrochemistry and mitigates parasitic reactions, irrespective of the immersion sequence in the same batch of ethanol solution. Consequently, the Zn||ODASnI\n                    <jats:sub>4<\/jats:sub>\n                    (ODA denotes 1,8\u2010octadiamine) coin cell demonstrated stable operation over 2500 cycles at 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a low additive cost of 1.43 \u00d7 10\n                    <jats:sup>\u22126<\/jats:sup>\n                    USD per cell. The pouch cell showed an average coulombic efficiency (CE) of 99.9% and 72% capacity retention after 1200 cycles, incurring an ultra\u2010low additive cost of 7.02\u00d7 10\n                    <jats:sup>\u22125<\/jats:sup>\n                    USD while delivering a high energy density of 143\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    (based on cathode mass). This work enabled durable and high\u2010performance ZIBs at minimal cost, providing a foundation for further exploration of low\u2010cost, scalable strategies in aqueous battery systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523567","type":"journal-article","created":{"date-parts":[[2026,2,4]],"date-time":"2026-02-04T06:21:43Z","timestamp":1770186103000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Ultra\u2010Low\u2010Cost Hydrophobic Organic Coating for Highly Reversible Zinc Anodes"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9165-758X","authenticated-orcid":false,"given":"Shixun","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Mechanical Engineering The University of Hong Kong  Hong Kong, S.A.R. P. R. China"},{"name":"Department of Materials Science and Engineering City University of Hong Kong  Hong Kong, S.A.R. P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanbo","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering The University of Hong Kong  Hong Kong, S.A.R. P. R. China"},{"name":"Department of Materials Science and Engineering City University of Hong Kong  Hong Kong, S.A.R. P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuoxi","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering The University of Hong Kong  Hong Kong, S.A.R. P. R. China"},{"name":"Department of Materials Science and Engineering City University of Hong Kong  Hong Kong, S.A.R. P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaoce","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering The University of Hong Kong  Hong Kong, S.A.R. P. R. 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China"},{"name":"Materials Innovation Institute For Life Sciences and Energy (MILES) HKU\u2010SIRI  Shenzhen China"},{"name":"Center For Energy Storage The University of Hong Kong  Hong Kong, Pokfulam 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