{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:49:48Z","timestamp":1791888588592,"version":"4.3.4"},"reference-count":48,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T00:00:00Z","timestamp":1773360000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T00:00:00Z","timestamp":1773360000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,5,4]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The heterobimetallic M\n                    <jats:sub>14<\/jats:sub>\n                    cluster [Co\n                    <jats:sub>3<\/jats:sub>\n                    Ga\n                    <jats:sub>2<\/jats:sub>\n                    ]H(\u03bc\n                    <jats:sup>2<\/jats:sup>\n                    \u2010GaTMP)\n                    <jats:sub>9<\/jats:sub>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    , TMP = 2,2,6,6\u2010tetramethylpiperidinyl) was obtained by treating CoCl\n                    <jats:sub>2<\/jats:sub>\n                    with GaTMP in the presence of Mg and H\n                    <jats:sub>2<\/jats:sub>\n                    as reduction additives.\n                    <jats:bold>1<\/jats:bold>\n                    features a trigonal bipyramidal Co\n                    <jats:sub>3<\/jats:sub>\n                    Ga\n                    <jats:sub>2<\/jats:sub>\n                    kernel with one substituent\u2010free Ga atom and one exposed GaH moiety inside a metallo\u2010environment of nine edge\u2010bridging GaTMP ligands. The resulting Co\n                    <jats:sub>3<\/jats:sub>\n                    Ga\n                    <jats:sub>11<\/jats:sub>\n                    cluster core mimics a packing motif of the structurally related intermetallic phase Co\n                    <jats:sub>2<\/jats:sub>\n                    Al\n                    <jats:sub>5<\/jats:sub>\n                    . The GaTMP ligands not only donate their lone pairs to the Co, but also to the exposed, bare Ga of the Co\n                    <jats:sub>3<\/jats:sub>\n                    Ga\n                    <jats:sub>2<\/jats:sub>\n                    kernel, thus contributing to the increase in delocalization over the M\n                    <jats:sub>14<\/jats:sub>\n                    core, according to bonding analysis. The synthesis of\n                    <jats:bold>1<\/jats:bold>\n                    represents proof\u2010of\u2010concept to steer the coordination of GaTMP to transition metal centers toward a kernel\u2010alloyed Co\/Ga cluster formation. This is rationalized by Mg\/H\n                    <jats:sub>2<\/jats:sub>\n                    \u2010induced Ga deprotection and TMP\u2010trapping in the\n                    <jats:italic>Hauser<\/jats:italic>\n                    \u2010base complex [Mg(TMP)(THF)\u03bc\n                    <jats:sup>2<\/jats:sup>\n                    Cl]\n                    <jats:sub>2<\/jats:sub>\n                    . The method bears potential for generalization, and first results were obtained for related Fe\/Ga clusters.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523687","type":"journal-article","created":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T17:17:36Z","timestamp":1773422256000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Molecular Mimics of Intermetallic Phases: Selective Alkylamide\u2010Ligand Deprotection Drives Co\/Ga Cluster Formation"],"prefix":"10.1002","volume":"65","author":[{"given":"Fabrizio E.","family":"Napoli","sequence":"first","affiliation":[{"name":"Department of Chemistry Technical University of Munich, TUM School of Natural Sciences, Chair of Inorganic and Metal\u2010Organic Chemistry  Garching Germany"},{"name":"Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-9277-8809","authenticated-orcid":false,"given":"Raphael","family":"B\u00fchler","sequence":"additional","affiliation":[{"name":"Department of Chemistry Technical University of Munich, TUM School of Natural Sciences, Chair of Inorganic and Metal\u2010Organic Chemistry  Garching Germany"},{"name":"Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4087-0070","authenticated-orcid":false,"given":"Johannes","family":"Stephan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Technical University of Munich, TUM School of Natural Sciences, Chair of Inorganic and Metal\u2010Organic Chemistry  Garching Germany"},{"name":"Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samia","family":"Kahlal","sequence":"additional","affiliation":[{"name":"Univ Rennes, CNRS, ISCR\u2010UMR  Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4469-7922","authenticated-orcid":false,"given":"Jean\u2010Yves","family":"Saillard","sequence":"additional","affiliation":[{"name":"Univ Rennes, CNRS, ISCR\u2010UMR  Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Gemel","sequence":"additional","affiliation":[{"name":"Department of Chemistry Technical University of Munich, TUM School of Natural Sciences, Chair of Inorganic and Metal\u2010Organic Chemistry  Garching Germany"},{"name":"Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7532-5286","authenticated-orcid":false,"given":"Roland A.","family":"Fischer","sequence":"additional","affiliation":[{"name":"Department of Chemistry Technical University of Munich, TUM School of Natural Sciences, Chair of Inorganic and Metal\u2010Organic Chemistry  Garching Germany"},{"name":"Catalysis Research Center Technical University of Munich  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,13]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00356"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02603"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00286D"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805897"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00733"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b00793"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00230"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308790"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.4019\/bjscc.81.20"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214315"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704667"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms3422"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/b927175a"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01021a"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.04.017"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04156"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00268F"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c03790"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805605"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51230d"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905920"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00344"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b03127"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/om200430t"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/b815319a"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2006.07.021"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004\u2010024\u201001110\u20109"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402149"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806039"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-024-01726-3"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201900302"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic801437n"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/om970913a"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.5b00992"},{"key":"e_1_2_7_36_1","doi-asserted-by":"crossref","unstructured":"C.Jones A.Stasch G. J.Moxey P. C.Junk andG. B.Deacon (Wiley Online Library 2009).","DOI":"10.1002\/ejic.200900407"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200802618"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar980135y"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100785a001"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1938.99.1.480"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925\u20108388(95)02045\u20104"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.intermet.2013.03.011"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b09675"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b11083"},{"key":"e_1_2_7_45_1","volume-title":"Magnetic, Electrical and Optical Properties and Applications of Intermetallic Compounds","author":"Westbrook J. H.","year":"2000"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20105088(79)90205\u20104"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.intermet.2004.08.003"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/9781118558409"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1093\/oso\/9780198551683.001.0001"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523687","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202523687","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523687","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:22:43Z","timestamp":1791886963000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202523687"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3,13]]},"references-count":48,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2026,5,4]]}},"alternative-id":["10.1002\/anie.202523687"],"URL":"https:\/\/doi.org\/10.1002\/anie.202523687","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,3,13]]},"assertion":[{"value":"2025-10-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-11","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e23687"}}