{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T00:51:28Z","timestamp":1783990288557,"version":"3.55.0"},"reference-count":112,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T00:00:00Z","timestamp":1768953600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,21]],"date-time":"2026-01-21T00:00:00Z","timestamp":1768953600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022FA1506100"],"award-info":[{"award-number":["2022FA1506100"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271112"],"award-info":[{"award-number":["22271112"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301092"],"award-info":[{"award-number":["22301092"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22071073"],"award-info":[{"award-number":["22071073"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["CCNU24JCPT016"],"award-info":[{"award-number":["CCNU24JCPT016"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005234","name":"Central China Normal University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100005234","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The radical\u2010mediated dearomatization of aromatic systems to generate cyclohexadienyl radical intermediates represents a crucial strategy for constructing three\u2010dimensional molecular architectures. Conventional approaches typically through\n                    <jats:italic>ipso<\/jats:italic>\n                    \u2010addition and subsequent proton\/oxygen\/carbon dioxide trapping to suppress rapid re\u2010aromatization, significantly constraining product diversity. Furthermore, dearomative bifunctionalization reactions\u2014which offer enhanced step\u2010 and atom\u2010economy\u2014remain substantially underdeveloped. Herein, we disclose a copper\u2010catalyzed radical dearomative 1,4\u2010 and 1,2\u2010carbosilylation strategy applicable to diverse unactivated (hetero)aromatic substrates to selectively construct spiro\u2010 or fused\u2010cyclic products. The resulting vinyl and allylic silanes serve as versatile synthetic handles for downstream transformations, enabling the rapid construction of sp\n                    <jats:sup>3<\/jats:sup>\n                    \u2010rich polycyclic scaffolds that are highly valuable in drug discovery. Mechanistic and DFT studies indicate that the reaction commences with copper(I)\u2010silicon\u2010mediated halogen atom transfer of readily available aryl iodides to generate aryl radicals. These reactive species exhibit dual pathways: direct\n                    <jats:italic>ipso<\/jats:italic>\n                    \u2010addition to aromatic rings or 1,5\u2010hydrogen atom transfer followed by alkyl radical\u2010mediated\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010addition. Subsequent trapping of the resulting dienyl radicals by copper(II)\u2010silicon species yields complex polycyclic systems containing cyclohexadienylsilicon frameworks with excellent chemo\u2010, regio\u2010 and diastereoselectivity. This methodology not only establishes a novel paradigm for copper\u2010catalyzed radical dearomative bifunctionalization but also provides an efficient radical\n                    <jats:italic>ipso\u2010<\/jats:italic>\n                    and\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010addition platform for synthesizing architecturally intricate polycyclic compounds.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523719","type":"journal-article","created":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T06:28:54Z","timestamp":1769063334000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Copper\u2010Catalyzed Regio\u2010 and Diastereoselective Dearomative Carbosilylation of Unactivated Arenes by Intercepting the Dienyl Radical"],"prefix":"10.1002","volume":"65","author":[{"given":"Jialian","family":"Zheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuili","family":"Liang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi\u2010Qing","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zunsheng","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhong","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"He","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beibei","family":"Yi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quanzhe","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuling","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinrong","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihan","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7436-8436","authenticated-orcid":false,"given":"Rui","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Pesticide Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  152 Luoyu Road Wuhan Hubei 430079 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,21]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm901241e"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.0c00829"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.1c01215"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010024\u201000623\u20100"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2009.12.046"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00091a012"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/B513226F"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013215"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202013215"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00018a002"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01563"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC03222A"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03506H"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00508C"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201027989\u20103"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00389K"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202101115"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006017"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006017"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00356C"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC04638E"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/jr9440000430"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/158585c0"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905485"},{"key":"e_1_2_7_22_2","first-page":"14427","volume":"131","year":"2011","journal-title":"Angew. Chem."},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05899"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03926"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010022\u201000065\u2010w"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215422"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202215422"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c06628"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201017085\u20109"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202100995"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201039633\u20109"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201016369\u20104"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058808\u20100"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00732"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317968"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202317968"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05572"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201800647"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/B307102M"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/b813246a"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100371y"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0031-1289668"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00328"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b03128"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.11.005"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b03655"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0037-1611918"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201018137\u2010w"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC02816A"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307074"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00311H"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202000636"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201901229"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00033"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201003730\u2010w"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00638"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00381"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00383"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00265"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00727K"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000860"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202000860"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009323"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202009323"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00738"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04230"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00965B"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407056"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202407056"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05651"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.7b00718"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2017.04.038"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm3010114"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1359-6446(03)02726-0"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210109"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202210109"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1055\/s\u20101977\u201024552"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104039(00)78044\u20100"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac198254010001"},{"key":"e_1_2_7_74_1","unstructured":"See Supporting Information for details."},{"key":"e_1_2_7_75_1","doi-asserted-by":"publisher","DOI":"10.2174\/1385272825666230727092717"},{"key":"e_1_2_7_76_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC03383C"},{"key":"e_1_2_7_77_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abq1274"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01690"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04621"},{"key":"e_1_2_7_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c02553"},{"key":"e_1_2_7_81_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024144\u20102"},{"key":"e_1_2_7_82_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303388"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202303388"},{"key":"e_1_2_7_83_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC02291E"},{"key":"e_1_2_7_84_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208232"},{"key":"e_1_2_7_84_2","volume":"134","year":"2023","journal-title":"Angew. Chem."},{"key":"e_1_2_7_85_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409310"},{"key":"e_1_2_7_85_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202409310"},{"key":"e_1_2_7_86_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06054"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516794"},{"key":"e_1_2_7_87_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202516794"},{"key":"e_1_2_7_88_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001194\u20105"},{"key":"e_1_2_7_89_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407293"},{"key":"e_1_2_7_89_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202407293"},{"key":"e_1_2_7_90_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2015.07.029"},{"key":"e_1_2_7_91_1","doi-asserted-by":"publisher","DOI":"10.1111\/cbdd.14239"},{"key":"e_1_2_7_92_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11172\u2010015\u20101005\u20104"},{"key":"e_1_2_7_93_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02607"},{"key":"e_1_2_7_94_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202100363"},{"key":"e_1_2_7_95_1","doi-asserted-by":"publisher","DOI":"10.3389\/fphar.2021.821518"},{"key":"e_1_2_7_96_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00749"},{"key":"e_1_2_7_97_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04400"},{"key":"e_1_2_7_98_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP02110K"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523719","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202523719","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202523719","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:38:20Z","timestamp":1773009500000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202523719"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,21]]},"references-count":112,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2026,2,23]]}},"alternative-id":["10.1002\/anie.202523719"],"URL":"https:\/\/doi.org\/10.1002\/anie.202523719","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,21]]},"assertion":[{"value":"2025-10-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-13","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e23719"}}