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Herein, the strongly electron\u2010accepting lattice oxygen was introduced onto CeO\n                    <jats:sub>2<\/jats:sub>\n                    via a hydroxylation\u2010induced Pt spontaneous redispersion strategy. The introduction of strongly electron\u2010accepting lattice oxygen enabled the highly reactive *CO intermediate formation, which triggered a novel thermodynamically favorable *CH\n                    <jats:sub>3<\/jats:sub>\n                    O\u2013*CO coupling to DMC synthesis. In addition, the lattice oxygen modification also markedly regulated the electron distribution of catalyst, thereby optimizing the adsorption strength of CO\n                    <jats:sub>2<\/jats:sub>\n                    and methanol and thus reducing the entire reaction barrier of *CH\n                    <jats:sub>3<\/jats:sub>\n                    O\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    coupling to DMC via a rate\u2010determining\u2010step shifting. Benefiting from these advantages, Pt\n                    <jats:sub>1<\/jats:sub>\n                    \/CeO\n                    <jats:sub>2<\/jats:sub>\n                    \u2013SO sample achieved a DMC yield of 62.1\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2014six\u2010fold higher than reported conventional catalyst under similar conditions. This work revealed the key role of strongly electron\u2010accepting lattice oxygen in the innovative DMC synthesis pathway, with potential applications in developing more efficient synthetic routes for methanol upgrading and CO\n                    <jats:sub>2<\/jats:sub>\n                    resource utilization.\n                  <\/jats:p>","DOI":"10.1002\/anie.202523737","type":"journal-article","created":{"date-parts":[[2025,12,19]],"date-time":"2025-12-19T11:49:16Z","timestamp":1766144956000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Strongly Electron\u2010Accepting Lattice Oxygen of CeO\n                    <sub>2<\/sub>\n                    for Highly Efficient Dimethyl Carbonate Synthesis from CO\n                    <sub>2<\/sub>\n                    and Methanol"],"prefix":"10.1002","volume":"65","author":[{"given":"Guoqiang","family":"Hou","sequence":"first","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinzhe","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Di","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoting","family":"Shan","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangyang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruosong","family":"He","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanzhu","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siyi","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang\u2010Kui","family":"Gu","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8769-4153","authenticated-orcid":false,"given":"Mingyue","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Power and Mechanical Engineering Wuhan University  Wuhan 430072 China"},{"name":"Perception and Effectiveness Assessment for Carbon\u2010Neutrality Efforts Engineering Research Center of Ministry of Education Institute for Carbon Neutrality Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,19]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b03217"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE00914K"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c08033"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202200087"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2023.01.008"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1080\/01614940.2019.1696609"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.04.112"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202513406"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie1012147"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214490"},{"key":"e_1_2_8_11_1","first-page":"0926","volume":"336","author":"Tian L.","year":"2023","journal-title":"Appl. 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