{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T20:59:38Z","timestamp":1793134778682,"version":"4.5.0"},"reference-count":29,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T00:00:00Z","timestamp":1768435200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T00:00:00Z","timestamp":1768435200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We demonstrate a unique approach to a 2D molecular slab in the solid state by designing a \u03c0\u2010extended hexaarylbenzene molecule, hexa(naphthothiophene diimide)\u2010substituted benzene (NTI6). The six naphthothiophene diimide (NTI) moieties of NTI6 were found to stand almost perpendicularly to the central benzene core both in solution and in the solid state, realizing a 3D shape\u2010persistent molecular structure. In the solid state, four of the six NTI units participated in \u03c0\u2010stacking intermolecular interactions in two different directions (the crystallographic\n                    <jats:italic>a<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>b<\/jats:italic>\n                    \u2010axis directions). In addition, the remaining two NTI units interacted with neighboring molecules in an edge\u2010to\u2010edge manner in the crystallographic (110) direction. Theoretical calculations showed that the intra\u2010 and intermolecular overlaps of LUMOs efficiently spread within the 2D molecular slab, ensuring the formation of a 2D interactive electronic structure suitable as the active channel of organic field\u2010effect transistors (OFETs). Indeed, the NTI6\u2010based solution\u2010processed OFETs exhibited electron mobility on the order of 10\n                    <jats:sup>\u22122<\/jats:sup>\n                    cm\n                    <jats:sup>2<\/jats:sup>\n                    V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    , corroborating the presence of a 2D electronic structure within the molecular slab.\n                  <\/jats:p>","DOI":"10.1002\/anie.202524473","type":"journal-article","created":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T05:21:37Z","timestamp":1768540897000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Construction of a Two\u2010Dimensional Molecular Slab with a \u03c0\u2010Extended Hexaarylbenzene Molecule"],"prefix":"10.1002","volume":"65","author":[{"given":"Haruki","family":"Sanematsu","sequence":"first","affiliation":[{"name":"RIKEN Center for Emergent Matter Science (CEMS)  2\u20101 Hirosawa Wako Saitama 351\u20100198 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rukiya","family":"Matsidik","sequence":"additional","affiliation":[{"name":"RIKEN Center for Emergent Matter Science (CEMS)  2\u20101 Hirosawa Wako Saitama 351\u20100198 Japan"},{"name":"Present address: Institut f\u00fcr Chemie Technische Universit\u00e4t Chemnitz  Stra\u00dfe der Nationen 62 Chemnitz 09111 Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Barun","family":"Dhara","sequence":"additional","affiliation":[{"name":"RIKEN Center for Emergent Matter Science (CEMS)  2\u20101 Hirosawa Wako Saitama 351\u20100198 Japan"},{"name":"Present address: School of Science and Engineering the Chinese University of Hong Kong  Shenzhen 518172 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6001-1129","authenticated-orcid":false,"given":"Kazuo","family":"Takimiya","sequence":"additional","affiliation":[{"name":"RIKEN Center for Emergent Matter Science (CEMS)  2\u20101 Hirosawa Wako Saitama 351\u20100198 Japan"},{"name":"Department of Chemistry Graduate School of Science Tohoku University  6\u20103 Aoba, Aramaki, Aoba\u2010ku Sendai Miyagi 980\u20138578 Japan"},{"name":"Advanced Institute for Materials Research (WPI\u2010AIMR) Tohoku University  2\u20101\u20101 Katahira, Aoba\u2010ku Sendai Miyagi 980\u20138577 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,15]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr050140x"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.71.2509"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.72.179"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201200862"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201905909"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja074841i"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201400289"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7828"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC04461J"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab1391"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00144"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509190"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0537171"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0238032"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC03476D"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20170298"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201901637"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201801655"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1RA00217A"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200501005"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200502105"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00809"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309680"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302587"},{"key":"e_1_2_5_25_1","unstructured":"Deposition numbers 2423267 (for NTI2) 2423268 (for NTI1) 2423269 (for NTI3) 2423270 (for NTI6) and 24232701 (for NTI4) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0258496"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6954"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9394"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aaz0632"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202524473","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202524473","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202524473","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:38:49Z","timestamp":1773009529000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202524473"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,15]]},"references-count":29,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2026,2,23]]}},"alternative-id":["10.1002\/anie.202524473"],"URL":"https:\/\/doi.org\/10.1002\/anie.202524473","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,15]]},"assertion":[{"value":"2025-11-05","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-08","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e24473"}}