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Electrochemical nitrate reduction to NH\n                    <jats:sub>2<\/jats:sub>\n                    OH suffers from dependence on external hydrogen sources, which often lead to the nitrite accumulation or over\u2010reduction of NH\n                    <jats:sub>2<\/jats:sub>\n                    OH to ammonia due to unbalanced hydrogenation intensity. Herein, we report the photoelectrochemical nitrate reduction to NH\n                    <jats:sub>2<\/jats:sub>\n                    OH (PENRH) using a bimetallic Bi\u2010 and Cu\u2010modified TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/CdS\/Sb\n                    <jats:sub>2<\/jats:sub>\n                    (S,Se)\n                    <jats:sub>3<\/jats:sub>\n                    semiconductor. Under AM 1.5\u00a0G illumination, the resulting photocathode achieves a Faradaic efficiency of 91.9% and a selectivity of 92.7% at 0.3 V\n                    <jats:sub>RHE<\/jats:sub>\n                    for NH\n                    <jats:sub>2<\/jats:sub>\n                    OH, while effectively suppressing side reactions. In situ characterization and theoretical calculations reveal that the synergy between Bi and Cu sites optimizes the adsorption of intermediates, promotes NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    protonation, and facilitates the rapid desorption of NH\n                    <jats:sub>2<\/jats:sub>\n                    OH, thereby preventing its over\u2010reduction. This system is successfully extended to the oxime synthesis by coupling in situ generated NH\n                    <jats:sub>2<\/jats:sub>\n                    OH with aldehydes or ketones, enabling efficient preparation of various oximes and demonstrating the broad applicability of PENRH. This work not only introduces a green photoelectrochemical approach for NH\n                    <jats:sub>2<\/jats:sub>\n                    OH synthesis, but also offers a new paradigm for the resource utilization of nitrate.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525106","type":"journal-article","created":{"date-parts":[[2026,2,2]],"date-time":"2026-02-02T10:52:52Z","timestamp":1770029572000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Ultralow\u2010Potential Photoelectrochemical Synthesis of Hydroxylamine and Oximes"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhenjiang","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University  Hohhot 010021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui\u2010Ting","family":"Gao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University  Hohhot 010021 China"},{"name":"College of Smart Materials and Future Energy Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University  Hohhot 010021 China"},{"name":"College of Smart Materials and Future Energy Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7449-2763","authenticated-orcid":false,"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering College of Energy Material and Chemistry Inner Mongolia Key Laboratory of Low Carbon Catalysis Inner Mongolia University  Hohhot 010021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,1]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061080\u2010x"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c09570"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c00256"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00222A"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12209\u2010025\u201000444\u20102"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304007"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14687"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010025\u201000879\u20104"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305491"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201038888\u20106"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ado1755"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202508442"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abl4822"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000713\u20103"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010023\u20101580\u20102"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202103683"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001330\u2010w"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04863"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509213"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01961"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010024\u20102417\u20109"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422443"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135758"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c04138"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202520139"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00077"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201055889\u20109"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413298"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506215"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c00544"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c12704"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00444"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202401585"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514840"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054204\u20102"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05466"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311196"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063996\u2010w"}],"container-title":["Angewandte 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