{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T18:31:46Z","timestamp":1784917906186,"version":"3.55.0"},"reference-count":42,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T00:00:00Z","timestamp":1770768000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T00:00:00Z","timestamp":1770768000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22372023"],"award-info":[{"award-number":["22372023"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21978032"],"award-info":[{"award-number":["21978032"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018617","name":"Liaoning Revitalization Talents Program","doi-asserted-by":"publisher","award":["XLYC2403019"],"award-info":[{"award-number":["XLYC2403019"]}],"id":[{"id":"10.13039\/501100018617","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,3,23]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Achieving carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction with water (H\n                    <jats:sub>2<\/jats:sub>\n                    O) on photothermal catalysts remains a major challenge. Here, we report a high\u2010density Ni single\u2010site catalyst based on a porous aromatic framework (PAF), which enables efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction in pure H\n                    <jats:sub>2<\/jats:sub>\n                    O under full\u2010spectrum illumination without the need for additives. Ni\u2010PAF achieves CO production rates of 25.64 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under Xe light and 229.04 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under concentrated sunlight, exceeding all reported results. Nitrogen\u2010rich groups anchor Ni single sites uniformly, serving as the active centers for the activation of CO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O. Calculations and experiments show that UV\u2013Vis light drives charge transfer, while IR absorption induces a localized temperature rise. Besides, the low thermal conductivity of PAF confines this heat, creating a thermal microenvironment that enhances charge migration and proton transfer, thereby accelerating CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion. These synergistic effects make Ni\u2010PAF a highly promising catalyst for solar\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction in H\n                    <jats:sub>2<\/jats:sub>\n                    O and offer new opportunities for designing efficient photothermal catalysts toward solar fuel production.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525685","type":"journal-article","created":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T04:40:27Z","timestamp":1770871227000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Solar\u2010Driven CO\n                    <sub>2<\/sub>\n                    and H\n                    <sub>2<\/sub>\n                    O Conversion Over a High\u2010Density Nickel Single\u2010Site Catalyst With Unprecedented CO Evolution Rate"],"prefix":"10.1002","volume":"65","author":[{"given":"Longfei","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dezhi","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiru","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shandong University  Jinan Shandong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianshuo","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huixin","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihao","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinkui","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9072-8331","authenticated-orcid":false,"given":"Min","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemistry Dalian University of Technology  Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,11]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.01.001"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010021\u201000289\u2010y"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06920"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415202"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054026\u20102"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u20100678\u20106"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201026219\u20106"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105482"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151479"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202110136"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202508924"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010020\u20102738\u20102"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214794"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.02.019"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057307\u20106"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4MH00161C"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10024B"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2022.125541"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c05233"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aesr.202200129"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202409531"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214259"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302495"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2022.130799"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202201943"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2021.05.010"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206544"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004841"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02978"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202204388"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000607\u20104"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC04063E"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c12832"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108513"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407578"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024647\u2010y"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0405086101"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP07459B"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317969"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201044753\u2010x"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201031474\u20102"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803514"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202525685","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202525685","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202525685","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,30]],"date-time":"2026-03-30T07:00:44Z","timestamp":1774854044000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202525685"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,11]]},"references-count":42,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2026,3,23]]}},"alternative-id":["10.1002\/anie.202525685"],"URL":"https:\/\/doi.org\/10.1002\/anie.202525685","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,11]]},"assertion":[{"value":"2025-11-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e25685"}}