{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:52:35Z","timestamp":1791888755325,"version":"4.3.4"},"reference-count":72,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T00:00:00Z","timestamp":1773792000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T00:00:00Z","timestamp":1773792000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,4,27]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    We demonstrate the synthesis of Cu(AlO\n                    <jats:sub>x<\/jats:sub>\n                    )\n                    <jats:sub>a<\/jats:sub>\n                    (SiO\n                    <jats:sub>y<\/jats:sub>\n                    )\n                    <jats:sub>b<\/jats:sub>\n                    clusters under the confines of MER zeolite, which hydrogenate CO\n                    <jats:sub>2<\/jats:sub>\n                    to methanol and dimethyl ether with 96% selectivity and a space time yield of 15.0 mmol\n                    <jats:sub>C<\/jats:sub>\n                    g\n                    <jats:sub>Cu<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 250 \u00b0C (4:1 H\n                    <jats:sub>2<\/jats:sub>\n                    :CO\n                    <jats:sub>2<\/jats:sub>\n                    and 5 MPa). A crucial aspect of the synthesis involves MER zeolite calcination, leading to framework dealumination and loss of long\u2010range order. These Cu(AlO\n                    <jats:sub>x<\/jats:sub>\n                    )\n                    <jats:sub>a<\/jats:sub>\n                    (SiO\n                    <jats:sub>y<\/jats:sub>\n                    )\n                    <jats:sub>b<\/jats:sub>\n                    clusters consist of a high density of coordinatively unsaturated aluminum sites, which are lacking in conventional copper catalysts with similar stoichiometry, and stabilize copper in a more oxidic form that is characterized by higher reduction temperatures. Other copper\u2010containing zeolites consisting of stable frameworks that do not dealuminate upon calcination (Cu\u2010Li\u2010FAU and Cu\u2010Li\u2010RHO zeolites) exhibit 99% selectivity to CO under the same reaction conditions. When compared with these catalysts and an industrial CuZnAl catalyst, kinetic analysis shows the Cu(AlO\n                    <jats:sub>x<\/jats:sub>\n                    )\n                    <jats:sub>a<\/jats:sub>\n                    (SiO\n                    <jats:sub>y<\/jats:sub>\n                    )\n                    <jats:sub>b<\/jats:sub>\n                    clusters are more intrinsically selective for methanol over the reverse water gas shift reaction at low CO\n                    <jats:sub>2<\/jats:sub>\n                    converions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525717","type":"journal-article","created":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T14:14:40Z","timestamp":1773843280000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coordinatively Unsaturated Aluminum Enables Methanol\u2010Selective CO\n                    <sub>2<\/sub>\n                    Hydrogenation With Zeolite\u2010Supported Copper Catalysts"],"prefix":"10.1002","volume":"65","author":[{"given":"Hwangho","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anvitha","family":"Puritipati","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youngkyu","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering University of California  Berkeley California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleg","family":"Mironov","sequence":"additional","affiliation":[{"name":"Chevron Technology Center  Richmond California 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