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However, their sustainability is severely limited due to acute CO poisoning, particularly at high current densities. To address this challenge, we develop Pt@NiM\u2010LDH electrocatalysts (M = Co, Mn, Cu, Fe) by anchoring Pt sites onto NiM layered double hydroxide (LDH) support via Pt\u2500O\u2500Ni bonding, which mitigates CO poisoning. Critically, it is found that applying periodic current polarity reversal to a symmetric Pt@NiCo\u2010LDH\u2016Pt@NiCo\u2010LDH electrode pair drastically attenuates CO\u2010poisoning. This system thereby enables concurrent productions of hydrogen and formate for at least 120\u00a0h at an industrial\u2010level current density (300\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) and a low cell voltage of 1.02\u00a0V, yielding a combined Faradaic efficiency of nearly 200%. Comprehensive experimental and theoretical studies reveal that the NiCo\u2010LDH support electronically modulates the Pt sites, suppressing both CO formation and adsorption. Furthermore, it is verified that the polarity reversal strategy weakens CO adsorption strength by inducing structural reconstruction of the electrical double layer (EDL). These synergistic mechanisms significantly enhance the sustainability of Pt\u2010based electrodes for coupled MOR\u2016HER electrolysis. This work thus provides a promising strategy for designing highly efficient and CO\u2010tolerant Pt\u2010based electrocatalytic systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525802","type":"journal-article","created":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T05:20:25Z","timestamp":1770268825000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Sustaining Methanol\u2010Oxidation and Hydrogen Evolution at Low Voltage by Applying Periodic Polarity Reversal on a Symmetric Pt\u2010Based Electrode Pair"],"prefix":"10.1002","volume":"65","author":[{"given":"Botao","family":"Zhu","sequence":"first","affiliation":[{"name":"Research Center for Eco\u2010Environmental Engineering Dongguan University of Technology  Dongguan China"},{"name":"Soochow Institute for Energy and Materials Innovation (SIEMIS) Jiangsu Key Laboratory of Advanced Negative Carbon Technologies School of Energy Soochow University  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