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Although organic electrodes are promising candidates, they often suffer from Coulombic repulsion and entropy\u2010induced disorder, leading to performance degradation. Herein, we propose a molecular\u2010engineering strategy based on geometric preorganization to construct low\u2010entropy proton transport pathways by designing a\n                    <jats:italic>\n                      C\n                      <jats:sub>3<\/jats:sub>\n                    <\/jats:italic>\n                    \u2010symmetric triangular molecule, 1, 3, 5\u2010tris (2, 6\u2010dioxo\u20101, 2, 5, 6\u2010tetrahydro\u20103, 4\u2010dihydropyrazinyl) benzene (DBH). Its rigid trigonal scaffold preorganizes C\u2550N and C\u2550O redox centers, enabling symmetric charge distribution to mitigate repulsion. Moreover, geometric confinement reduces configurational disorder and restricts accessible microstates, directing proton migration along defined pathways while preserving electronic delocalization. As a result, the DBH electrode delivers high and ultrafast proton\u2010storage capacity, reaching 277.9\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and retaining 207.8\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    even at 100\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . When assembled into a full cell, the device achieves 100% capacity retention after 30\u00a0000 cycles, along with an energy density of 111.97\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a power density of 40 441.2\u00a0W kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    . These results demonstrate that triangular preorganization combined with entropy regulation enables organic electrodes to exhibit high proton\u2010storage capacity, rapid kinetics, and exceptional long\u2010term stability.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525809","type":"journal-article","created":{"date-parts":[[2026,1,10]],"date-time":"2026-01-10T14:02:49Z","timestamp":1768053769000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Geometric Preorganization Enables Entropy\u2010Constrained Proton Migration for Ultrafast and Stable Aqueous Proton Batteries"],"prefix":"10.1002","volume":"65","author":[{"given":"He","family":"Liu","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu University of Science and Technology  Zhenjiang 212003 P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Lin","family":"Yang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory for UV Light\u2010Emitting Materials and Technology Department of Physics Northeast Normal University  Changchun Jilin 130024 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Congcong","family":"Ni","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  Shanghai 200444 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6568-3215","authenticated-orcid":false,"given":"Minjie","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Jiangsu University of Science and Technology  Zhenjiang 212003 P.R. 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