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In CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation, efforts have largely emphasized CO\n                    <jats:sub>2<\/jats:sub>\n                    activation while overlooking how to design active phase for the co\u2010conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    and the kinetically distinct byproduct CO. Here, it is found that adding CO to CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2013H\n                    <jats:sub>2<\/jats:sub>\n                    feeds boosts methanol productivity by up to 2.2\u2010fold via a pronounced synergistic promotion of both CO\n                    <jats:sub>2<\/jats:sub>\n                    and CO hydrogenation over a Cu\u2013ZnZrO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    catalyst. In situ spectroscopy reveals that CO accelerates Zn reduction and migration onto Cu, increasing Zn\n                    <jats:sup>0<\/jats:sup>\n                    \/Cu ratio, Zn\n                    <jats:sup>2+<\/jats:sup>\n                    \/Cu, and Cu\n                    <jats:sup>+<\/jats:sup>\n                    \/Cu fraction, while reducing exposed surface Cu from 42% to 19%. This CO\u2010induced restructuring enriches Zn exposure, drives CuZn alloy formation, and creates abundant CuZn alloy\u2013ZnO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    interfaces that stabilize Cu\n                    <jats:sup>+<\/jats:sup>\n                    sites. These interfaces enable a cooperative dual\u2010pathway mechanism: CO\n                    <jats:sub>2<\/jats:sub>\n                    is hydrogenated mainly via the formate route at alloy\u2013ZnO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    sites, whereas CO follows the formyl route on Cu sites. Additionally, in situ\u2010formed water accelerates conversion of the rate\u2010determining CH\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>*<\/jats:sup>\n                    intermediate in the CO pathway. Together, CO\u2010driven evolution of active sites, synergistic dual\u2010pathway catalysis, and water\u2010assisted promotion yield highly efficient methanol synthesis from mixed CO\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    feeds.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525886","type":"journal-article","created":{"date-parts":[[2026,1,6]],"date-time":"2026-01-06T04:58:00Z","timestamp":1767675480000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["CO\u2010Induced Reconstruction of Cu\u2013ZnZrO\n                    <i>\n                      <sub>x<\/sub>\n                    <\/i>\n                    Catalyst Enables Synergistic CO\n                    <sub>2<\/sub>\n                    \/CO Co\u2010Hydrogenation to Methanol"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiaojing","family":"Wu","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Catalysis of Gansu Province State Key Laboratory of Natural Product Chemistry College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou Gansu 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanqing","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  No.18, Tianshui Middle Road Lanzhou Gansu 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianian","family":"Cheng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Catalysis of Gansu Province State Key Laboratory of Natural Product Chemistry College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou Gansu 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jieyun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key 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