{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T03:22:10Z","timestamp":1792725730643,"version":"4.5.0"},"reference-count":29,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T00:00:00Z","timestamp":1769040000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T00:00:00Z","timestamp":1769040000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22322811"],"award-info":[{"award-number":["22322811"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22438012"],"award-info":[{"award-number":["22438012"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278388"],"award-info":[{"award-number":["22278388"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508378"],"award-info":[{"award-number":["22508378"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,2,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Overcoming the intrinsic trade\u2010off between ionic conductivity and mechanical robustness remains a long\u2010standing challenge for anion exchange membranes (AEMs). Here, we report a helical tetra\u2010functional building block derived from tetraphenyl\u2010ethylene (TPE) that enables the simultaneous construction of interconnected ion\u2010transport channels and mechanically reinforced polymer networks. The non\u2010coplanar molecular configuration of TPE generates continuous microporous pathways, which establish efficient pathways for ion transport and enable 22.6% enhancement in H\n                    <jats:sub>2<\/jats:sub>\n                    O\/OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    species diffusion. Meanwhile, restricted intramolecular rotations of the phenyl rings dissipate mechanical stress and prevent brittle fracture. Concurrently, the tetra\u2010functional structure yields a cross\u2010linked network, synergistically endowing the exceptional mechanical robustness of 79% enhancement in transverse tensile strength and 43% improvement in longitudinal hardness. Anion exchange membrane water electrolyzers (AEMWEs) operating under harsh conditions of temperature and high alkalinity were used for application evaluation. The QTPE\u2010x\u2010configurated cell delivered an enhanced current density and exceptional operational stability. The molecular\u2010level design strategy successfully decouples ionic conductivity and mechanical integrity, providing a general framework for the development of high\u2010performance AEMs in sustainable energy conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.202525998","type":"journal-article","created":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T13:03:39Z","timestamp":1769087019000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Molecular\u2010Level Energy Dissipation and Micropore Engineering Synergistically Enhance Anion Exchange Membrane Performance"],"prefix":"10.1002","volume":"65","author":[{"given":"Cui","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Applied Chemistry School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and Engineering School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanjie","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Applied Chemistry School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyan","family":"Xiao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Polymer Science and Engineering School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolin","family":"Ge","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Applied Chemistry School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9221-5126","authenticated-orcid":false,"given":"Tongwen","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Precision and Intelligent Chemistry Department of Applied Chemistry School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,1,22]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201022612\u20103"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100372\u20108"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.143442"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311509"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058638\u20100"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.101976"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010019\u20101782\u20102"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adr3834"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001210\u20108"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512275"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.12.010"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418435"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405738"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400764"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422504"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201038350\u20107"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061735\u20109"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418435"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2025.124578"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001364\u20100"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507763"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00263"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202512553"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2011.08.020"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202500931"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.4c00037"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2024.04.188"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2016.01.003"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2023.107516"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202525998","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202525998","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202525998","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:39:27Z","timestamp":1773009567000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202525998"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,1,22]]},"references-count":29,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2026,2,23]]}},"alternative-id":["10.1002\/anie.202525998"],"URL":"https:\/\/doi.org\/10.1002\/anie.202525998","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,1,22]]},"assertion":[{"value":"2025-11-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-09","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e25998"}}