{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T15:38:10Z","timestamp":1783093090289,"version":"3.54.6"},"reference-count":47,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T00:00:00Z","timestamp":1772755200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,6]],"date-time":"2026-03-06T00:00:00Z","timestamp":1772755200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22276022"],"award-info":[{"award-number":["22276022"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,4,13]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Tandem catalytic systems for HCHO oxidation are generally regarded as a relay process comprising intermediate (e.g., Methyl formate, MF) generation on zeolites and subsequent intermediates\u2010to\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion on supported metal catalysts. Here, a new cascade pathway mediated by the secondary intermediate methanol (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH) over ZSM\u20105\/Pt\u2010\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    tandem catalyst is proposed, which is composed of physically mixed ZSM\u20105 and Pt\u2010\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    with an overall Pt content of only 0.3 wt%. In this system, the CH\n                    <jats:sub>3<\/jats:sub>\n                    OH is generated directly via MF decomposition on acidic ZSM\u20105 and subsequently serves as the primary active intermediate on Pt\u2010\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst, enabling efficient HCHO\u2010to\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    complete conversion under ambient conditions. The deep studies with Pd\u2010 and Ag\u2010based tandem systems further reveal that the reaction pathway is steered by the intrinsic reactivity of intermediates on supported metal catalysts: CH\n                    <jats:sub>3<\/jats:sub>\n                    OH\u2010mediated cascade routes dominate in Pt\u2010 and Pd\u2010containing systems, whereas MF remains the sole reactive intermediate over Ag\u2010based tandem catalysts. Additionally, we demonstrate that the molecular diffusion of key intermediate within ZSM\u20105 plays a decisive role in proximity\u2010dependent catalytic behavior. Specifically, the strong adsorption affinity and interfacial accumulation of CH\n                    <jats:sub>3<\/jats:sub>\n                    OH on ZSM\u20105 necessitate close spatial proximity between the zeolite and Pt catalyst, in contrast to the weaker adsorption affinity of MF.\n                  <\/jats:p>","DOI":"10.1002\/anie.2172359","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T22:59:02Z","timestamp":1773010742000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Steering the Reaction Pathway of Tandem Catalytic Oxidation of HCHO Under Ambient Condition via Methanol Intermediate"],"prefix":"10.1002","volume":"65","author":[{"given":"Yue","family":"Ding","sequence":"first","affiliation":[{"name":"Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China) School of Environmental Science and Technology Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China) School of Environmental Science and Technology Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cui","family":"Dong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China) School of Environmental Science and Technology Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu Chun","family":"Chang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China) School of Environmental Science and Technology Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0948-2029","authenticated-orcid":false,"given":"Zhenping","family":"Qu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education, China) School of Environmental Science and Technology Dalian University of Technology  Dalian 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