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Herein, we developed CeO\n                    <jats:sub>x<\/jats:sub>\n                    \u2010modified Co\n                    <jats:sub>2<\/jats:sub>\n                    C catalysts. At a Co\/Ce molar ratio of 99, the catalyst achieved a C\n                    <jats:sub>2+<\/jats:sub>\n                    hydrocarbon space\u2010time yield of 106 mmol\u00a0g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 35% CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion (300\u00b0C, 3\u00a0MPa), outperforming all reported Co\u2010based catalysts and comparable to some Fe\u2010based catalysts. Characterizations and kinetic studies reveal that highly dispersed CeO\n                    <jats:sub>x<\/jats:sub>\n                    interacts with Co, forming abundant and intimately contacted interfaces and effectively tuning the electronic structure of Co\n                    <jats:sub>2<\/jats:sub>\n                    C. The Co\n                    <jats:sub>2<\/jats:sub>\n                    C\u2013CeO\n                    <jats:sub>x<\/jats:sub>\n                    electronic interaction enhances CO adsorption and H\n                    <jats:sub>2<\/jats:sub>\n                    activation, accelerating the rate\u2010determining CO hydrogenation and ultimately boosting C\n                    <jats:sub>2+<\/jats:sub>\n                    hydrocarbon formation. This work provides a feasible strategy for designing efficient Co\n                    <jats:sub>2<\/jats:sub>\n                    C\u2010based catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1002\/anie.2179385","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T07:38:06Z","timestamp":1791877086000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Enhancing the Formation of C\n                    <sub>2+<\/sub>\n                    Hydrocarbons in CO\n                    <sub>2<\/sub>\n                    Hydrogenation Through Co\n                    <sub>2<\/sub>\n                    C\/CeO\n                    <sub>x<\/sub>\n                    Interactions"],"prefix":"10.1002","author":[{"given":"Hui","family":"Gao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine 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