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Simultaneously achieving high activity and long\u2010term stability is a prerequisite for the industrialization of urea electrosynthesis. In this study, we propose an electron bridge strategy based on a Pd\n                    <jats:sub>1<\/jats:sub>\n                    and Ni\n                    <jats:sub>1<\/jats:sub>\n                    dual single\u2010atom alloy to boost the electrocatalytic activity and durability for urea electrosynthesis. The single\u2010atom Ni\n                    <jats:sub>1<\/jats:sub>\n                    sites act as electron bridges to promote charge transfer from Cu to Pd\n                    <jats:sub>1<\/jats:sub>\n                    sites, leading to charge\u2010polarized Pd\u2013Cu sites, which upshift the d\u2010band center and improve oxidation resistance of the catalyst. Consequently, the Pd\n                    <jats:sub>1<\/jats:sub>\n                    and Ni\n                    <jats:sub>1<\/jats:sub>\n                    dual single\u2010atom sites simultaneously accelerates both carbon dioxide reduction and nitrates reduction half\u2010reactions, while facilitating the first C\u2013N coupling step. The Pd\n                    <jats:sub>1<\/jats:sub>\n                    and Ni\n                    <jats:sub>1<\/jats:sub>\n                    dual single\u2010atom alloys deliver a urea yield rate of 541.6\u00a0mmol g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a urea Faradaic efficiency of 57.3%. Remarkably, this catalyst achieves a record durability of 1700\u00a0h at a current density of 40\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work provides new insights into the synergistic catalysis of complex multi\u2010molecule reactions through cooperative multiple active sites.\n                  <\/jats:p>","DOI":"10.1002\/anie.2196422","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T06:33:30Z","timestamp":1789540410000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electron Bridge Enhanced Charge Polarization Enables Efficient and Ultra\u2010Long Stable Urea Electrosynthesis"],"prefix":"10.1002","author":[{"given":"Fan","family":"Wu","sequence":"first","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Zhejiang Key Laboratory of Organosilicon Material Technology, College of Material Chemistry and Chemical Engineering Hangzhou Normal University  Hangzhou Zhejiang P. R. 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