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However, its strong\u2010acidity and weak\u2010interface\u2010bonding inherences remain great challenges for commercially desirable PSCs. To overcome the limitation, we proposed the orientation\u2010engineered interfacial bi\u2010anchoring molecules with a symmetric linear donor\u2013acceptor\u2013donor (D\u2013A\u2013D) structured N\u2010oxide\u2010based building block. The D\u2013A\u2013D structure with intramolecular push\u2013pull electron effects features superior hole\u2010selective ability than the widely used donor units, endowing effective hole\u2010transport planar. However, the bilateral N\u2010oxide functional groups (N\n                    <jats:sup>+<\/jats:sup>\n                    \u2010O\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) in the acceptor bipyridine introduce a steric effect to drive the D\u2013A\u2013D planar in both in\u2010plane and out\u2010of\u2010plane directions, effectively promoting the hole extraction. Moreover, the reversely oriented N\n                    <jats:sup>+<\/jats:sup>\n                    \u2010O\n                    <jats:sup>\u2212<\/jats:sup>\n                    function groups can firmly adsorb on ITO substrate and perovskite buried surface, respectively, constructing an interfacial bi\u2010anchoring connection. This molecular configuration considerably promotes the photothermal tolerance,\u00a0connective strength as well as energy\u2010level alignment at perovskite\/HTLs interface, enabling superior charge extraction and durability. Consequently, BPyDO\u2010TPA\u2010based inverted PSCs achieve an impressive efficiency of 26.53%, ranking as one of the highest efficiencies among nonphosphonic acid small\u2010molecule transporting materials. BPyDO\u2010TPA\u2010based devices also demonstrate excellent operational stability, retaining 94.82% of its initial efficiency after MPP tracking for 1000\u00a0h at 85\u00a0\u00b0C.\n                  <\/jats:p>","DOI":"10.1002\/anie.2298813","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T08:51:06Z","timestamp":1787129466000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Orientation\u2010Engineered Interfacial Bi\u2010Anchoring Molecules for Efficient and Stable Perovskite Solar Cells"],"prefix":"10.1002","volume":"65","author":[{"given":"Bo","family":"Feng","sequence":"first","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education School of Smart Materials and Future Energy Anhui Normal University Anhui China"},{"name":"School of Physics and Electronic Science Engineering Research Center of Nano\u2010photonics and Advanced Instrument 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