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Here, we report a self\u2010assembled Pd\n                    <jats:sub>8<\/jats:sub>\n                    water\u2010soluble molecular barrel\n                    <jats:bold>MB<\/jats:bold>\n                    that encapsulates and enables effective solubilization of fullerenes in water, overcoming these limitations to form a homogeneous supramolecular catalytic system in water. The host\u2010guest complex\n                    <jats:bold>\n                      (C\n                      <jats:sub>70<\/jats:sub>\n                      )\n                      <jats:sub>2<\/jats:sub>\n                      @MB\n                    <\/jats:bold>\n                    exhibited a significantly enhanced photosensitization ability, effectively catalysing both the aerobic oxidative dehydrogenation of tetrahydroquinolines to quinolines and sulfide oxidation to sulfoxides with high selectivity. To our knowledge, this system represents the first\n                    <jats:bold>\n                      C\n                      <jats:sub>70<\/jats:sub>\n                    <\/jats:bold>\n                    \u2010catalysed aerobic oxidative dehydrogenation of tetrahydroquinoline to the corresponding quinolines. Importantly,\n                    <jats:bold>\n                      (C\n                      <jats:sub>70<\/jats:sub>\n                      )\n                      <jats:sub>2<\/jats:sub>\n                      @MB\n                    <\/jats:bold>\n                    exhibits \u223c12\u2010fold improvement in photocurrent response relative to free\n                    <jats:bold>\n                      C\n                      <jats:sub>70<\/jats:sub>\n                    <\/jats:bold>\n                    , suggesting superior charge separation and transfer within the confined environment of\n                    <jats:bold>MB<\/jats:bold>\n                    . Furthermore, NMR titrations and computational studies revealed the\n                    <jats:bold>MB<\/jats:bold>\n                    \u2019s rectangular cavity co\u2010binds substrates at the longer\n                    <jats:bold>MB<\/jats:bold>\n                    edges, alongside the encapsulated fullerenes. The combined effects of solubilization, aggregation prevention, enhanced charge separation, and substrate co\u2010binding together contribute to the enhanced photosensitization ability of\n                    <jats:bold>\n                      C\n                      <jats:sub>70<\/jats:sub>\n                    <\/jats:bold>\n                    upon encapsulation within\n                    <jats:bold>MB<\/jats:bold>\n                    in an aqueous solution.\n                    <jats:bold>MB<\/jats:bold>\n                    thus, functions as an enzyme\u2010like molecular reactor harnessing fullerene photochemistry for light\u2010driven transformations in water.\n                  <\/jats:p>","DOI":"10.1002\/anie.2304851","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:49:44Z","timestamp":1773028184000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Fullerene Photosensitization Within a Self\u2010Assembled Hollow Pd (II) Architecture for Light\u2010Driven Oxidation Reactions in Water"],"prefix":"10.1002","volume":"65","author":[{"given":"Sailendra","family":"Pradhan","sequence":"first","affiliation":[{"name":"Department of Inorganic and Physical Chemistry Indian Institute of Science  Bengaluru India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valiyakath Abdul","family":"Rinshad","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Physical Chemistry Indian Institute of Science  Bengaluru India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Neal","family":"Hickey","sequence":"additional","affiliation":[{"name":"Department of Chemical and Pharmaceutical Sciences University of Trieste  Trieste Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7425-7381","authenticated-orcid":false,"given":"Partha 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