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However, achieving site\u2010specific control over their high\u2010pressure optical response remains a great challenge. In this study, we report a zero\u2010dimensional manganese chloride, (HIm)\n                    <jats:sub>6<\/jats:sub>\n                    [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    \u2219MnCl\n                    <jats:sub>6<\/jats:sub>\n                    ] (HIm = imidazolium), which concurrently incorporates both tetrahedral and octahedral Mn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    centers within a single lattice. Under pressure, the red emission of [MnCl\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>4\u2212<\/jats:sup>\n                    exhibits a pronounced and linear redshift and intensity attenuation. However, the green emission of [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    remains stable in both peak position and intensity, serving as a rigid energetic anchor. By leveraging the invariant green emission as an internal reference and the pressure\u2010sensitive red emission as a probe, a self\u2010calibrated pressure sensing system is achieved. Synchrotron high\u2010pressure x\u2010ray diffraction, in situ optical spectroscopy and density functional theory calculations demonstrate that this decoupled response originates from the large structural compressibility of the [MnCl\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>4\u2212<\/jats:sup>\n                    octahedra and high rigidity of the [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    tetrahedra. Our findings demonstrate that hybrid organic\u2010inorganic crystals represent a promising class of self\u2010calibrated optical sensing materials for next\u2010generation metrology.\n                  <\/jats:p>","DOI":"10.1002\/anie.2354490","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T06:11:54Z","timestamp":1791871914000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Self\u2010Calibrated Luminescence Sensing Under Pressure in a Hybrid Manganese Halide"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-1605-1849","authenticated-orcid":false,"given":"Lian\u2010Cai","family":"An","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Qingdao University  Qingdao China"},{"name":"Collaborative Innovation Center of Materials Science Nankai University  Tianjin 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