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This two\u2010step process avoids photoirradiation, chromatography, and external redox agents. 11 Unprotected monosaccharides react with high 1,2\u2010\n                    <jats:italic>trans<\/jats:italic>\n                    selectivity, tolerating diverse functional groups and heteroarenes. The utility is showcased by two\u2010step assembly of gliflozin drugs, their analogues and Neopetrosin C. This platform positions glycosyl sulfonyl hydrazides as a versatile radical source and a scalable alternative to photoinduced C\u2010glycosylation.\n                  <\/jats:p>","DOI":"10.1002\/anie.2385204","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:56:05Z","timestamp":1785938165000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unprotected\n                    <i>C<\/i>\n                    \u2010Aryl Glycosides From Native Sugars via Glycosyl Sulfonyl Hydrazides: A Thermal Cap\u2010and\u2010Glycosylate Strategy"],"prefix":"10.1002","volume":"65","author":[{"given":"Shuai\u2010Peng","family":"Gao","sequence":"first","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis Jiangxi Normal University  Nanchang 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Carbohydrate Synthesis Jiangxi Normal University  Nanchang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5909-2582","authenticated-orcid":false,"given":"Xiang\u2010Guo","family":"Hu","sequence":"additional","affiliation":[{"name":"National Engineering Research Center for Carbohydrate Synthesis Jiangxi Normal University  Nanchang 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