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Prior studies demonstrated that SSZ\u201013 aluminosilicate with strong acidity as zeolite component promotes hydrogen transfer to yield alkanes but also accelerates coking\/deactivation, while SAPO\u201034 silicoaluminophosphate with moderate acidity greatly improves the catalytic stability but yields insufficient alkane selectivity. Herein, we designed a new OXZEO bifunctional catalytic system based on trace Platinum species (0.11\u00a0wt.%) confined within SAPO\u201034 coupling with ZnZrO\n                    <jats:sub>x<\/jats:sub>\n                    solid solution (ZnZrO\n                    <jats:sub>x<\/jats:sub>\n                    \/Pt@SAPO\u201034), achieving a high CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion (46.1%) with C\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>0<\/jats:sup>\n                    \u2010C\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>0<\/jats:sup>\n                    selectivity (94.1%), and giving a superior stable lifetime over 200\u00a0h. The excellent catalytic performance is attributed to the confined hydrogen spillover mechanism over Pt species in SAPO\u201034 that suppresses carbon deposition and enables efficient H\n                    <jats:sub>2<\/jats:sub>\n                    dissociation and spillover to significantly promote light olefin hydrogenation to corresponding alkanes.\n                  <\/jats:p>","DOI":"10.1002\/anie.2445993","type":"journal-article","created":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T08:56:04Z","timestamp":1775552164000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Integrating Hydrogen Dissociation and Spillover Sites Into Platinum Confined SAPO\u201034 Zeolite Unlocks Efficient CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Light Alkanes"],"prefix":"10.1002","volume":"65","author":[{"given":"Jinsong","family":"Cui","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials\u2010Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University  Nanjing China"},{"name":"Suzhou National Laboratory  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials\u2010Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2609-1660","authenticated-orcid":false,"given":"Jie","family":"Tuo","sequence":"additional","affiliation":[{"name":"Suzhou National Laboratory  Suzhou China"},{"name":"State Key Laboratory of Petroleum Molecular and Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University  Shanghai 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