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Although the electrosynthesis of some C\n                    <jats:sub>2<\/jats:sub>\n                    products (e.g., ethylene, acetate, and ethanol) has achieved certain success, the generation of glycolate is still beyond the scope of existing electrocatalytic technologies. Here, we report the electrochemical reaction of direct conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    to glycolate in aqueous media under ambient conditions using unsaturated Cu sites as the catalyst, with a production rate of glycolate up to 305\u00a0\u00b1\u00a024\u00a0mmol\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Further mechanism studies have shown that the key to glycolate generation is the formation and timely desorption of the *OHCCHO intermediate after C\u2013C coupling, followed by a disproportionation reaction with base to generate the product. This work provides a successful case for the sustainable synthesis of glycolic acid from CO\n                    <jats:sub>2<\/jats:sub>\n                    in aqueous media, which represents a new product from electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    RR.\n                  <\/jats:p>","DOI":"10.1002\/anie.2505348","type":"journal-article","created":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T14:34:20Z","timestamp":1783434860000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Direct Electrosynthesis of Glycolate From Carbon Dioxide"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiao","family":"Chen","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-9225-5257","authenticated-orcid":false,"given":"Shuaiqiang","family":"Jia","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxin","family":"Zhai","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiapeng","family":"Jiao","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries Xi'an Polytechnic University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengke","family":"Dong","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Xue","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Deng","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanghui","family":"Xia","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingjie","family":"Cheng","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3017-379X","authenticated-orcid":false,"given":"Chunjun","family":"Chen","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6266-8290","authenticated-orcid":false,"given":"Haihong","family":"Wu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyuan","family":"He","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0440-809X","authenticated-orcid":false,"given":"Buxing","family":"Han","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Green Chemistry and Chemical Processes State Key Laboratory of Petroleum Molecular &amp; Process Engineering School of Chemistry and Molecular Engineering East China Normal University  Shanghai China"},{"name":"Institute of Eco\u2010Chongming  Shanghai China"},{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Colloid and Interface and Thermodynamics CAS Research\/Education Center for Excellence in Molecular Sciences, Center for Carbon Neutral Chemistry Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,7]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422183"},{"key":"e_1_2_8_3_1","unstructured":"Glycolic Acid Market Size By Purity Level (99% Purity 70% Purity 60% Purity 30% Purity) Grade (Cosmetic Grade Technical Grade Pharmaceutical Grade Industrial Grade) Application (Personal Care & Dermatology Tanning & Dyeing Agriculture Medical Food) \u2010 Growth Trends Regional Share Competitive Intelligence Forecast Report 2025\u20102037 https:\/\/www.researchnester.com\/cn\/reports\/glycolic\u2010acid\u2010market\/4911."},{"key":"e_1_2_8_4_1","unstructured":"D. J.Loder \u201cProcess for Manufacture of Glycolic Acid.\u201d United States Patent Office No. US2152852 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