{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T05:40:26Z","timestamp":1791438026734,"version":"4.3.3"},"reference-count":48,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T00:00:00Z","timestamp":1778544000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T00:00:00Z","timestamp":1778544000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22478278 22308246"],"award-info":[{"award-number":["22478278 22308246"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,7,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Immobilizing cation\u2010type organic molecules at the cathode represents a transformative strategy for enhancing the electrocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) in acidic or pure water. However, the investigation of anion\u2010type organic molecules is missing, and the roles of cations and anions are not well understood, especially in the membrane electrode assembly (MEA) configuration. Employing an ionic\u2010confinement strategy mediated by a solid\u2010state electrolyte, we systematically investigate the influence of cation\u2010 and anion\u2010type organic molecules on CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. Our findings show that cations in both cation\u2010 and anion\u2010type molecules play a crucial role in inhibiting the hydrogen evolution reaction and promoting CO\n                    <jats:sub>2<\/jats:sub>\n                    RR in MEA. Utilizing an anion\u2010type organic molecule, we achieved exceptional CO Faradaic efficiencies of 98.4% in H\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4<\/jats:sub>\n                    media (pH = 1) and 95.8% in pure water\u2010fed MEAs on Ag. Additionally, with cation\u2010type organic molecules, we demonstrated robust operational stability of 150 h in H\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4<\/jats:sub>\n                    (pH = 1) electrolyte and 460 h in an ultra\u2010low potassium concentration (2\u00a0mM) acidic electrolyte in MEA configuration. This work establishes a versatile framework for achieving high\u2010efficiency, long\u2010term CO\n                    <jats:sub>2<\/jats:sub>\n                    electrolysis across diverse electrolyte environments, highlighting its potential for industrial\u2010scale application.\n                  <\/jats:p>","DOI":"10.1002\/anie.2577753","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T09:17:18Z","timestamp":1778577438000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Achieving High Selectivity and Stability in Electrocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction in Acidic Media via Ion Confinement"],"prefix":"10.1002","volume":"65","author":[{"given":"Xuelei","family":"Lang","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Taiyuan University of Technology  Taiyuan Shanxi P.R. 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