{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T17:44:31Z","timestamp":1786211071815,"version":"build-2736575974"},"reference-count":72,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2026,6,10]],"date-time":"2026-06-10T00:00:00Z","timestamp":1781049600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,10]],"date-time":"2026-06-10T00:00:00Z","timestamp":1781049600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22175148"],"award-info":[{"award-number":["22175148"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["9610480"],"award-info":[{"award-number":["9610480"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["9610663"],"award-info":[{"award-number":["9610663"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["7020103"],"award-info":[{"award-number":["7020103"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["7006007"],"award-info":[{"award-number":["7006007"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["9680301"],"award-info":[{"award-number":["9680301"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,8,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Metal\u2013organic frameworks (MOFs) have shown great promise for electrochemical carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction into value\u2010added chemicals\/fuels, thereby supporting the balance of carbon\u2010neutral energy cycle. The multi\u2010carbon (C\n                    <jats:sub>2+<\/jats:sub>\n                    ) production on MOF electrocatalysts is of great significance but remains challenging due to inefficient C\u2013C coupling. Here, we report the atomic coordination regulation of MOF nanostructures (Cu\u2010Trz\u2010Br) for efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction by rationally designing dual\u2010site Cu catalysts. The crystallographic structure of Cu\u2010Trz\u2010Br is determined by three\u2010dimensional electron diffraction and Rietveld refinement against high\u2010resolution powder X\u2010ray diffraction data, which feature unique mixed coordination modes of Cu\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    Br\n                    <jats:sub>2<\/jats:sub>\n                    and Cu\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    sites. In CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction, Cu\u2010Trz\u2010Br demonstrates much enhanced selectivity toward C\n                    <jats:sub>2+<\/jats:sub>\n                    products compared to common counterparts with only Cu\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    sites, enabling efficient C\n                    <jats:sub>2+<\/jats:sub>\n                    production under industrial\u2010level current density. In situ studies and theoretical calculations reveal that the coordination regulation of Cu\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    Br\n                    <jats:sub>2<\/jats:sub>\n                    sites promotes CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and activation, as well as effectively enhances local *CO availability near Cu\u2010Trz\u2010Br, thereby facilitating C\u2013C coupling toward C\n                    <jats:sub>2+<\/jats:sub>\n                    products.\n                  <\/jats:p>","DOI":"10.1002\/anie.2590405","type":"journal-article","created":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T06:11:51Z","timestamp":1781158311000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Atomic Coordination Engineering of MOF Nanostructures for CO\n                    <sub>2<\/sub>\n                    Electroreduction to High\u2010Value Multi\u2010Carbon Products at Industrial\u2010Level Current Density"],"prefix":"10.1002","volume":"65","author":[{"given":"Juan","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM) City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nana","family":"Yan","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lutong","family":"Shan","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Manchester UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Lyu","sequence":"additional","affiliation":[{"name":"Multi\u2010scale Porous Materials Center Institute of Advanced Interdisciplinary Studies &amp; School of Chemistry and Chemical Engineering Chongqing University  Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingbo","family":"Wa","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengkun","family":"Hao","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fu","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingzheng","family":"Shao","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM) City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9648-4024","authenticated-orcid":false,"given":"Yunhao","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM) City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guozhi","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang","family":"Meng","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM) City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaohui","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenliang","family":"Ye","sequence":"additional","affiliation":[{"name":"Department of Power Engineering, North China Electric Power University Baoding China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7261-2098","authenticated-orcid":false,"given":"Yanwei","family":"Lum","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shibo","family":"Xi","sequence":"additional","affiliation":[{"name":"Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency For Science, Technology and Research) Jurong Island Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3494-7000","authenticated-orcid":false,"given":"Daliang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Multi\u2010scale Porous Materials Center Institute of Advanced Interdisciplinary Studies &amp; School of Chemistry and Chemical Engineering Chongqing University  Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5392-3915","authenticated-orcid":false,"given":"Peng","family":"Guo","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of Lower\u2010Carbon Catalysis Technology Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"},{"name":"China University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3133-6503","authenticated-orcid":false,"given":"Zhanxi","family":"Fan","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Branch of National Precious Metals Material Engineering Research Center (NPMM) City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"Hong Kong Institute For Clean Energy City University of Hong Kong  Kowloon Hong Kong SAR China"},{"name":"City University of Hong Kong Shenzhen Research Institute  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,10]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005540\u20100"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000552\u20102"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057307\u20106"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2204666119"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00931E"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.3c01156"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202106766"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202102151"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2021.01.007"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404574"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07502"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18508"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00678"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.3c00567"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010021\u20103448\u20102"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100450\u2010y"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02124"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201037898\u20108"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201027768\u20106"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407090"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051928\u2010z"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503417"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001132\u20105"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00206"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00571"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057095\u2010z"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00835D"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213436"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215333"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00843B"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402278"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202214707"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216021"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001142"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100097"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202100090"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04746"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202400432"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114648"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108388"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c12389"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204967"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.2c01083"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00335"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016882"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213583"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.07.016"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10812"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13847"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01393"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.2010.1202"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052520619006711"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41596\u2010022\u201000720\u20108"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201034237\u20101"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0907444909047337"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202301536"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06820"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201031427\u20109"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201035993\u20104"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11450"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01562"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04638"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u20100594\u20109"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201020961\u20107"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402979"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400160"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411591"},{"key":"e_1_2_8_70_1","article-title":"Enhanced Local CO Coverage on Cu Quantum Dots for Boosting Electrocatalytic CO2 Reduction to Ethylene","volume":"34","author":"Wang Y.","year":"2024","journal-title":"Advanced Functional Materials"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01466"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b06811"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201016111\u20100"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2590405","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.2590405","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2590405","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T17:26:24Z","timestamp":1786209984000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.2590405"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,10]]},"references-count":72,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2026,8,10]]}},"alternative-id":["10.1002\/anie.2590405"],"URL":"https:\/\/doi.org\/10.1002\/anie.2590405","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,10]]},"assertion":[{"value":"2026-03-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-29","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e2590405"}}