{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T07:19:24Z","timestamp":1791875964933,"version":"4.3.4"},"reference-count":35,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T00:00:00Z","timestamp":1775779200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T00:00:00Z","timestamp":1775779200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475110"],"award-info":[{"award-number":["22475110"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121005"],"award-info":[{"award-number":["22121005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20554"],"award-info":[{"award-number":["U23A20554"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006606","name":"Natural Science Foundation of Tianjin Municipality","doi-asserted-by":"publisher","award":["25JCZDJC01220"],"award-info":[{"award-number":["25JCZDJC01220"]}],"id":[{"id":"10.13039\/501100006606","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,5,18]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Unraveling the active sites of Cu\/Zn catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol continues to pose a fundamental challenge, especially in clarifying the precise role of Zn promoters. Previous studies have predominantly emphasized the chemical state of Zn, while often neglecting accompanying structural changes in the Cu host. Here, we report the first direct observation of lattice expansion in nanocrystalline Cu within a bulk Zn\/Cu single\u2010atom alloy\u2014a geometric distortion that elevates the\n                    <jats:italic>d<\/jats:italic>\n                    \u2010band center of Cu and increases interatomic Cu distances. As evidenced by combined in situ experiments and density functional theory (DFT) calculations, these structural modifications promote the activation of both H\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    , steering the reaction toward the *HCOO pathway and substantially enhancing methanol production at notably low temperatures. Our findings deliver unprecedented insight into Zn's promotional mechanism and significantly advance the mechanistic understanding of Cu\/Zn catalysts for methanol synthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.2739572","type":"journal-article","created":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T04:56:28Z","timestamp":1775883388000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Evidence for Zn\u2010Promoted Methanol Synthesis at Low Temperature Over Zn\/Cu Single\u2010Atom Alloy Catalyst"],"prefix":"10.1002","volume":"65","author":[{"given":"Bo","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Lei","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yizhen","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyi","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanping","family":"Sui","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Information Functional Materials 2020 X\u2010Lab Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2306-095X","authenticated-orcid":false,"given":"Pengyi","family":"Tang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Information Functional Materials 2020 X\u2010Lab Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xize","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahe","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7407-5521","authenticated-orcid":false,"given":"Jian\u2010Gong","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0286-4182","authenticated-orcid":false,"given":"Donghai","family":"Mei","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0396-1846","authenticated-orcid":false,"given":"Peng","family":"Cheng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Frontiers Science Center for New Organic Matter and Key Laboratory of Advanced Energy Materials Chemistry (MOE) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,10]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adn9388"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2025.103216"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00614A"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00723"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00502H"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1821029116"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00122B"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.08.016"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00599"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c08043"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00726"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202330"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2025.116460"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c04480"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11540"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abj7747"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal3573"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216803"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000625\u2010x"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c05750"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg8389"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00078"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00490"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00611"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00967"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010018\u20100125\u20105"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010021\u201000974\u20105"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316888"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CP03880K"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/0039\u20106028(96)80007\u20100"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.81.2819"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010018\u20100054\u20100"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.04.012"},{"key":"e_1_2_7_35_1","first-page":"893","article-title":"Industrial Catalysts","volume":"336","author":"Behrens M.","year":"2012","journal-title":"The Active Site of Methanol Synthesis over Cu"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000840\u20100"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2739572","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.2739572","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2739572","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,20]],"date-time":"2026-06-20T13:30:32Z","timestamp":1781962232000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.2739572"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,10]]},"references-count":35,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2026,5,18]]}},"alternative-id":["10.1002\/anie.2739572"],"URL":"https:\/\/doi.org\/10.1002\/anie.2739572","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,10]]},"assertion":[{"value":"2026-02-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-03-27","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e2739572"}}