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Nevertheless, their symmetric electron density distribution hampers the polarization and subsequent scission of the O\u2500O bond. In this work, a Co\u2013Zn DAC with axial sulfur coordination (Co\u2500Zn@SNC) was constructed via a molecular\u2010cage encapsulation method. The as\u2010synthesized catalyst demonstrated outstanding oxygen reduction reaction (ORR) activity across a wide pH range, with half\u2010wave potentials of 0.902\u00a0V in 0.1\u00a0M KOH, 0.817\u00a0V in 0.1\u00a0M PBS, and 0.809\u00a0V in 0.1\u00a0M HClO\n                    <jats:sub>4<\/jats:sub>\n                    . Theoretical calculations revealed that the axially coordinated S not only modulated the orbital and electronic structure of the Co active center but also collaborated with the nearby Zn site to induce an asymmetric charge distribution within the Co\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    , thereby shifting the catalytic activity closer to the peak of the Sabatier volcano plot. The zinc\u2013air battery (ZAB) and microbial fuel cell (MFC) assembled with the Co\u2500Zn@SNC cathode exhibited peak power densities of 166.36\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1.505\u00a0W m\n                    <jats:sup>\u22122<\/jats:sup>\n                    , respectively, as well as good stability. The present work provided fundamental insights into the precise regulation and underlying mechanism of DACs, offering a viable strategy for the rational design of advanced electrocatalysts for energy storage and conversion applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.2911991","type":"journal-article","created":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T15:52:48Z","timestamp":1789833168000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Breaking Charge Symmetry in Co\u2013Zn Dual\u2011Atom Catalyst With Axial Sulfur Coordination for Efficient Oxygen Reduction Reaction"],"prefix":"10.1002","author":[{"given":"Jixiang","family":"Zou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Space Power\u2010Sources MIIT Key Laboratory of Critical Materials Technology for New Energy Consversion and Storage MOE Engineering Research Center for Electrochemical Energy Storage and Carbon Neutrality in Cold Regions School of Chemistry and Chemical Engineering Harbin Institute of Technology  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lixiao","family":"Shen","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen China"},{"name":"College of Physics and Optoelectronic Engineering Shenzhen University  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhishuai","family":"Yuan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Space Power\u2010Sources MIIT Key Laboratory of Critical Materials Technology for New Energy Consversion and Storage MOE Engineering Research Center for Electrochemical Energy Storage and Carbon Neutrality in Cold Regions School of Chemistry and Chemical Engineering Harbin Institute of Technology  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5259-8054","authenticated-orcid":false,"given":"Mei","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Space Power\u2010Sources MIIT Key Laboratory of Critical Materials Technology for New Energy Consversion and Storage MOE Engineering Research Center for Electrochemical Energy Storage and Carbon Neutrality in Cold Regions School of Chemistry and Chemical Engineering Harbin Institute of Technology  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5124-393X","authenticated-orcid":false,"given":"Lei","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Space Power\u2010Sources MIIT Key Laboratory of Critical Materials Technology for New Energy Consversion and Storage MOE Engineering Research Center for Electrochemical Energy Storage and Carbon Neutrality in 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