{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:57:17Z","timestamp":1790528237386,"version":"4.1.0"},"reference-count":44,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The activity\u2013stability trade\u2010off has long been a Gordian knot for metal\u2013organic frameworks (MOFs) photocatalyst. Here, a high\u2010entropy UiO\u201067 MOF (HE\u2010UiO\u201067) constructed with 2,2'\u2010bipyridine\u20105,5'\u2010dicarboxylic acid as the linker and ZrCeHfSnFe metal nodes was designed to induce a hydroxyl radical (\u2022OH) negative\u2010feedback mechanism to disentangle the trade\u2010off in methane oxygenation with H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    . When the \u2022OH concentration generated at Fe sites exceeds the tolerance threshold of adjacent Ce\u2500O bonds, the Ce centers are reconstructed by ligand abstraction into the unsaturated Ce sites for driving the interfacial H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    conversion into low oxidative O\n                    <jats:sub>2<\/jats:sub>\n                    or \u2022OOH species in high\u2010entropy metal nodes, thereby blocking the MOFs damage. This unique radical negative feedback process in HE\u2010UiO\u201067 can maximize the concentration of radicals while maintain the stable operation for over 100 h in an ambient pressure flow\u2010phase system, substantially exceeding most of the previous reports. Under visible light irradiation, HE\u2010UiO\u201067 photocatalyst exhibits an outstanding liquid oxygenate yield of up to 9732\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a selectivity of 93.5%. Overall, this study opens up a promising strategy for designing efficient and durable photocatalysts to break the activity\u2013stability trade\u2010off in CH\n                    <jats:sub>4<\/jats:sub>\n                    oxygenation.\n                  <\/jats:p>","DOI":"10.1002\/anie.2967863","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:43:39Z","timestamp":1790527419000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Radical Negative\u2010Feedback in High Entropy UiO\u201067 to Break the Activity\u2013Stability Trade\u2010Off in Photocatalytic Oxygenation of CH\n                    <sub>4<\/sub>"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-2971-8598","authenticated-orcid":false,"given":"Guanwei","family":"Peng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection College of Chemistry Fuzhou University  Fuzhou P. 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