{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T18:40:32Z","timestamp":1792262432290,"version":"4.4.0"},"reference-count":53,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271052"],"award-info":[{"award-number":["22271052"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22571044"],"award-info":[{"award-number":["22571044"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,19]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    A divergent visible light\u2010induced photocycloaddition (PCA) of benzene derivatives with allenes is described, enabled by efficient sensitization of simple arene moieties using an iridium triplet sensitizer. The reactions, governed by the tethered allene chain, proceed selectively through two distinct pathways:\n                    <jats:italic>para<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010cycloaddition. The\n                    <jats:italic>para<\/jats:italic>\n                    \u2010cycloaddition pathway, influenced by substituent effect, can further deliver a range of formal\n                    <jats:italic>meta<\/jats:italic>\n                    \u2010type products following a subsequent di\u2010\u03c0\u2010methane rearrangement. In comparison, the\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010cycloaddition pathway produces linear tricyclic cyclobutenes via cascade electrocyclic reactions. Modulated by the substituent on the allene moiety, a sequential di\u2010\u03c0\u2010methane rearrangement furnishes different formal\n                    <jats:italic>meta<\/jats:italic>\n                    \u2010type products. Control experiments, together with density functional theory (DFT) calculations, provide a comprehensive understanding of the underlying reaction pathways.\n                  <\/jats:p>","DOI":"10.1002\/anie.2982207","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T05:12:52Z","timestamp":1788153172000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Controllable Dearomative Photocycloaddition of Triplet Benzenes With Allenes"],"prefix":"10.1002","volume":"65","author":[{"given":"Licheng","family":"Lu","sequence":"first","affiliation":[{"name":"Research Center for Molecular Recognition and Synthesis Department of Chemistry Fudan University  Shanghai P. R. China"},{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Fudan University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2259-2700","authenticated-orcid":false,"given":"Ping","family":"Lu","sequence":"additional","affiliation":[{"name":"Research Center for Molecular Recognition and Synthesis Department of Chemistry Fudan University  Shanghai P. R. China"},{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Fudan University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,30]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00389K"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c01651"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00005"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1071\/ch23029"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac199062081597"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00017a017"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00018a002"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002845"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr0680336"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00255a058"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201908619"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915731"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110009"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.687"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709766"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.07.010"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00412"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC04421A"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00190C"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03302"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b12965"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg0720"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07726"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000784\u20105"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305622"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416215"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058285\u20105"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aeb8506"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6c05917"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05463"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.016"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201016369\u20104"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05899"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03926"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000886\u20100"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14669"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01983"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/B913749A"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00024B"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00334"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202401143"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198206201"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4025963"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol800806a"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo4002307"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6c00429"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216817"},{"key":"e_1_2_8_49_1","unstructured":"A UV light\u2010induced PCA of benzene with allene was reported in Ref [46] where an ortho\u2010derived intermediate was in\u2010situ trapped using an alcohol."},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900936"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112695"},{"key":"e_1_2_8_52_1","unstructured":"Deposition Numbers CCDC 2564767 (for 3p) 2564768 (for 6o) and 2564769 (for 5v) Contain the Supplementary Crystallographic Data for this Paper. These Data Are Provided Free of Charge by the Joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures Service."},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar000113n"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2982207","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.2982207","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.2982207","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T17:41:18Z","timestamp":1792258878000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.2982207"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,30]]},"references-count":53,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2026,10,19]]}},"alternative-id":["10.1002\/anie.2982207"],"URL":"https:\/\/doi.org\/10.1002\/anie.2982207","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,30]]},"assertion":[{"value":"2026-06-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e2982207"}}