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Herein, we report that two dynamic processes designed to operate orthogonally, reversible Au(I)\u2500C\n                    <jats:italic>\u03c3<\/jats:italic>\n                    \u2010bond exchange and exchangeable Cu(I)\u2500N coordination, can be coupled to promote metal\u2010templated dynamic reorganization. This process leads to the formation of an interlocked metal\u2010complex precursor, which reductive elimination then converts into a [2]catenane composed of two mechanically interlocked, fully \u03c0\u2010conjugated, nitrogen\u2010doped [12]CPP\u2010based nanohoops. Computational analyses provide insight into possible Cu(I)\u2010templated intermediates involved in the formation of the interlocked structure. The embedded sp\n                    <jats:sup>2<\/jats:sup>\n                    nitrogen atoms further provide coordination sites for guest\u2010dependent biasing of the co\u2010conformational mechanical helical chirality. This work establishes dynamic metal\u2010templated reorganization as a strategy for constructing strained, topologically complex \u03c0\u2010conjugated architectures beyond the reach of conventional single\u2010interaction self\u2010assembly.\n                  <\/jats:p>","DOI":"10.1002\/anie.3010868","type":"journal-article","created":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T16:06:42Z","timestamp":1791043602000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Metal\u2010Templated Dynamic Reorganization of Macrocyclic Gold Complexes Toward an\n                    <i>N<\/i>\n                    \u2010Doped Cycloparaphenylene Catenane"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2798-1203","authenticated-orcid":false,"given":"Hiromichi","family":"Yokoyama","sequence":"first","affiliation":[{"name":"Department of Chemical Science and Engineering National Institute of Technology 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