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Here, we report a novel near\u2010infrared (NIR) photothermal catalytic platform by depositing silver nanoparticles onto a bipyridinium radical\u2010functionalized covalent triazine framework (CTF) for the carboxylative cyclization of propargylic amines with CO\n                    <jats:sub>2<\/jats:sub>\n                    without external heating. It is found that, under 808\u00a0nm laser irradiation, the catalyst delivers a 6.9\u2010fold enhancement in photothermal catalytic activity relative to its bipyridinium\u2010free analogue. Due to the exceptional penetration depth of near\u2010infrared light, this photothermal catalytic system achieves a record turnover frequency of 2952.1\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    even in the presence of translucent barriers. The stabilizing effect of extended \u03c0\u2010conjugation within the CTF matrix on bipyridinium radicals maintains the high photothermal catalytic activity over 10 consecutive cycles. Furthermore, this photothermal catalytic system demonstrates practical scalability, allowing for gram\u2010scale (\u223c10\u00a0g) one\u2010pot synthesis of an oxazolidinone product under natural sunlight. This work not only provides a novel approach for promoting value\u2010added CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion under mild conditions, but also demonstrates the transformative potential of bipyridinium radicals in designing high\u2010performance NIR photothermal catalytic systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.3026199","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T09:23:48Z","timestamp":1787390628000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Photothermally Boosted CO\n                    <sub>2<\/sub>\n                    Conversion by Silver Nanoparticles Anchored on a Bipyridinium Radical\u2010Functionalized Covalent Triazine Framework"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-1393-6021","authenticated-orcid":false,"given":"Xiao\u2010Dong","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Key Laboratory for Green Media and Reactions Henan International Joint Laboratory of Green Chemistry Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Dong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Key Laboratory for Green Media and Reactions Henan International Joint Laboratory of Green Chemistry Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingyi","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Key Laboratory for Green Media and Reactions Henan International Joint Laboratory of Green Chemistry Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9024-1726","authenticated-orcid":false,"given":"Xiaopeng","family":"Xuan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Key Laboratory for Green Media and Reactions Henan International Joint Laboratory of Green Chemistry Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9397-954X","authenticated-orcid":false,"given":"Suojiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Longzihu New Energy Laboratory Henan University Zhengzhou Henan P. R. China"},{"name":"Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2417-4630","authenticated-orcid":false,"given":"Jianji","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Key Laboratory for Green Media and Reactions Henan International Joint Laboratory of Green Chemistry Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan P. R. China"},{"name":"College of Chemistry and Molecular Sciences Longzihu New Energy Laboratory Henan University Zhengzhou Henan P. R. 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