{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T11:56:10Z","timestamp":1791460570098,"version":"4.3.4"},"reference-count":54,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22232004"],"award-info":[{"award-number":["22232004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Rare earth (RE) regulation has emerged as an effective strategy for improving hydrogen evolution reaction (HER), but RE kinetic behaviors are widely discussed from an adsorption energy perspective, with neglectful apparent activation energy (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    ) and entropy (\u0394\n                    <jats:sup>\u2021<\/jats:sup>\n                    <jats:italic>S<\/jats:italic>\n                    ) contributions. This work develops an effective tandem catalyst of Ru anchored on MoS\n                    <jats:sub>2<\/jats:sub>\n                    decorated with Tm single\u2010atom sites (Ru\/Tm SAs\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    ), and reveals a tandem Ru\u2010Tm site\u2010derived entropy\u2013enthalpy tradeoff in alkaline HER. The Ru\/Tm SAs\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    delivers a low overpotential of 8 mV at 10 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    toward HER and achieves 1.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at only 1.74 V with excellent operating life over 600 h in anion\u2010exchange membrane water electrolysis. Temperature\u2010dependent kinetic analysis reveals that Tm incorporation reshapes the HER kinetic origin through a potential\u2010dependent entropy\u2010enthalpy tradeoff mechanism. At low overpotentials, Tm reduces\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    to improve reaction activation; At elevated overpotentials, the amplified \u0394\n                    <jats:sup>\u2021<\/jats:sup>\n                    <jats:italic>S<\/jats:italic>\n                    contribution offsets the elevated energy barrier of HER. In situ and theoretical characterizations verify that Tm incorporation not only reorganizes an interfacial hydrogen\u2010bond network to underpin \u0394\n                    <jats:sup>\u2021<\/jats:sup>\n                    <jats:italic>S<\/jats:italic>\n                    \u2010correlated kinetic behavior, but also tunes the electronic structure of Ru and mitigates overabundant electronic reconstruction upon H* adsorption. This work provides a new insight into understanding the role of RE in regulating alkaline HER kinetics.\n                  <\/jats:p>","DOI":"10.1002\/anie.3060071","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T11:22:12Z","timestamp":1791458532000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tandem Ru\u2013Tm Sites on MoS\n                    <sub>2<\/sub>\n                    Tune Entropy\u2013Enthalpy Tradeoff for Enhanced Alkaline Hydrogen Evolution"],"prefix":"10.1002","author":[{"given":"Yu","family":"Zhu","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wentao","family":"Xue","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-5040-9262","authenticated-orcid":false,"given":"Meng","family":"Li","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoheng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujie","family":"Wang","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhou","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 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Research (WPI\u2010AIMR) Tohoku University  Sendai Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4468-0821","authenticated-orcid":false,"given":"Yawen","family":"Tang","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0411-645X","authenticated-orcid":false,"given":"Gengtao","family":"Fu","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Long\u2010duration Energy Storage Battery Technology Jiangsu Collaborative Innovation Center of Biomedical Functional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 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