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However, photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction (PCCR) to acetic acid typically suffers from low acetic acid yields and selectivity, constrained by competing reactions from ethanol and inefficient C\u2013C coupling. Herein, we report a chiral mesostructured ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    (CMZI) photocatalyst that achieves a remarkable acetic acid yield of 962\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a high selectivity of 97.3%. This performance stems from synergistic chirality\u2010induced spin polarization and sulfur site catalysis. Spin polarization stabilizes the triplet OCCO intermediate to enhance C\u2013C coupling, while sulfur sites on ZnIn\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    {102} facets thermodynamically and kinetically favor acetic acid formation. This work offers critical insights into catalytic strategies of the efficient synthesis of high\u2010value multicarbon products and expanding the variety of synthetic products from CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction.\n                  <\/jats:p>","DOI":"10.1002\/anie.3091087","type":"journal-article","created":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T16:51:01Z","timestamp":1775926261000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Spin\u2010Polarized Chiral ZnIn\n                    <sub>2<\/sub>\n                    S\n                    <sub>4<\/sub>\n                    for Targeted Solar\u2010Driven CO\n                    <sub>2<\/sub>\n                    Reduction to Acetic Acid"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-0520-5198","authenticated-orcid":false,"given":"Yongping","family":"Cui","sequence":"first","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis, School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs Shanghai Jiao Tong University  Shanghai China"},{"name":"Department of Energy and Environmental Materials Suzhou National Laboratory  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanbo","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010qiang","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and 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