{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T06:10:56Z","timestamp":1790143856566,"version":"4.0.1"},"reference-count":72,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["W2511056"],"award-info":[{"award-number":["W2511056"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52333005"],"award-info":[{"award-number":["52333005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22505009"],"award-info":[{"award-number":["22505009"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["Z230018"],"award-info":[{"award-number":["Z230018"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The efficiency bottleneck of organic solar cells (OSCs) is predominantly hindered by severe non\u2010radiative energy loss (\u0394\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    ), which primarily originates from strong electron\u2010phonon coupling and detrimental charge recombination into darker state traps. Herein, we designed and synthesized a highly rigid and polarized dimeric acceptor, DY\u2010SO by incorporating a sulfone bridged unit. It is revealed that the sulfone bridge's steric hindrance restricts backbone torsion and suppresses molecular vibration, enabling DY\u2010SO with significantly reduced reorganization energy compared to small molecule L8\u2010BO, which reduces non\u2010radiative triplet trapping (CT\u2192T\n                    <jats:sub>1<\/jats:sub>\n                    ) and yields photoluminescence quantum yield (PLQY) of 11.70% and exceptionally low \u0394\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>3<\/jats:sub>\n                    of 0.149\u00a0eV. Upon deploying DY\u2010SO into the D18:L8\u2010BO baseline matrix to evaluate its photovoltaic potential, we further discovered that the inclusion of this rigid dimer successfully tames the film\u2010formation kinetics, effectively suppressing the excessive self\u2010agglomeration inherent to rigid structures and promoting more ordered molecular packing and a favorable phase\u2010separated morphology. Benefiting from these synergistic modulations, the optimal ternary D18:L8\u2010BO:DY\u2010SO OSC achieves an outstanding power conversion efficiency of 21.13% (certified as 20.70%). This work demonstrates that by introducing structurally rigidified, highly polarized dimeric acceptor to suppress molecular vibrational coupling, and mitigate non\u2010radiative dissipation is of great significance for improving the performance of OSCs.\n                  <\/jats:p>","DOI":"10.1002\/anie.3111048","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T05:54:08Z","timestamp":1790142848000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Vibrational Suppression and Aggregation Control via a Rigid Dimeric Acceptor for 21.13% Organic Solar Cells"],"prefix":"10.1002","author":[{"given":"Qingao","family":"Chen","sequence":"first","affiliation":[{"name":"Hangzhou International Innovation Institute Beihang University  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinyang","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Zhejiang University  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Di","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7747-9054","authenticated-orcid":false,"given":"Haiming","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Zhejiang University  Hangzhou P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2019-3458","authenticated-orcid":false,"given":"Xianqiang","family":"Xie","sequence":"additional","affiliation":[{"name":"School of Chemistry Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyong","family":"You","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering\/Film Energy Chemistry For Jiangxi Provincial Key Laboratory (FEC) Nanchang University  Nanchang P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7908-9874","authenticated-orcid":false,"given":"Laju","family":"Bu","sequence":"additional","affiliation":[{"name":"School of Chemistry Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7829-7308","authenticated-orcid":false,"given":"Guanghao","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Chemistry Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xunchang","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Flexible Optoelectronic Materials and Technology (Ministry of Education), School of Optoelectronic Materials &amp; Technology Jianghan University  Wuhan P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-7554-262X","authenticated-orcid":false,"given":"Renqiang","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Flexible Optoelectronic Materials and Technology (Ministry of Education), School of Optoelectronic Materials &amp; Technology Jianghan University  Wuhan P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawei","family":"Deng","sequence":"additional","affiliation":[{"name":"Hangzhou International Innovation Institute Beihang University  Hangzhou P.R. China"},{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-6322-2140","authenticated-orcid":false,"given":"Mingxu","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Physics State Key Laboratory of Crystal Materials Shandong University  Jinan P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shilin","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-5799-1190","authenticated-orcid":false,"given":"Jiali","family":"Song","sequence":"additional","affiliation":[{"name":"Hangzhou International Innovation Institute Beihang University  Hangzhou P.R. China"},{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7839-3199","authenticated-orcid":false,"given":"Yanming","family":"Sun","sequence":"additional","affiliation":[{"name":"Hangzhou International Innovation Institute Beihang University  Hangzhou P.R. China"},{"name":"School of Chemistry Beihang University  Beijing P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100181\u20105"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adj3654"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500282"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010024\u201002087\u20105"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500357"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506415"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202517341"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.06.020"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.5c00291"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-019-0573-5"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201037526\u20105"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.08.003"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE02598F"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2017.09.020"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045512\u20108"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.53"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.04.002"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000843\u20104"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302452"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413309"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201040806\u20109"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201015215\u2010x"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201030927\u2010y"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00174A"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202111855"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE06043E"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202102559"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201010098\u2010z"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201203246"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202316039"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00199"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00363"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201504120"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202520162"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201013292\u20101"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202424430"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901872"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010017\u20100005\u20101"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01220G"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107476"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010019\u20100093\u20104"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE03989J"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01864G"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.12.007"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202101733"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05848H"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209350"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.46"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107361"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418353"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202508209"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202413913"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202408858"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201018378\u20109"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514741"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010025\u201000880\u2010x"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2023.12.009"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.08.006"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104678"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201068731\u20107"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.73194"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00576"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201605779"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.01.006"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202089"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507529"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202519588"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202500129"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047707\u20105"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2023.09.001"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424502"},{"key":"e_1_2_8_73_1","first-page":"1","article-title":"Super\u2010Snell Scanning Light\u2010field Display for Ultrawide\u2010Angle High\u2010resolution Glasses\u2010free Three\u2010dimensional Displays","volume":"20","author":"He H.","year":"2026","journal-title":"Nature Photonics"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.3111048","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.3111048","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.3111048","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T05:54:10Z","timestamp":1790142850000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.3111048"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,22]]},"references-count":72,"alternative-id":["10.1002\/anie.3111048"],"URL":"https:\/\/doi.org\/10.1002\/anie.3111048","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,22]]},"assertion":[{"value":"2026-05-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-16","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e3111048"}}