{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:07:51Z","timestamp":1790003271868,"version":"4.0.1"},"reference-count":80,"publisher":"Wiley","issue":"39","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["YQR23095"],"award-info":[{"award-number":["YQR23095"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012246","name":"Priority Academic Program Development of Jiangsu Higher Education Institutions","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012246","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008674","name":"Yazaki Memorial Foundation for Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008674","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP25KF0021 JP23H01442"],"award-info":[{"award-number":["JP25KF0021 JP23H01442"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,21]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Boron phosphide (BP) nanowires represent a rare 1D semiconductor, combining outstanding chemical stability, ultrahigh hardness, and high thermal conductivity. However, their controlled growth and optical functionality remain largely unexplored due to irregular morphologies, toxic precursors, and complex synthesis routes. Here, we develop a supersaturation\u2010engineered chemical vapor transport (CVT) strategy to synthesize air\u2010stable, single\u2010crystalline cubic BP nanowires with tunable diameters. Strain\u2010engineered Raman spectroscopy reveals pronounced phonon broadening and symmetry\u2010selective frequency shifts, uncovering strong strain\u2013phonon coupling. The inherent noncentrosymmetry and nanoscale confinement further induce highly anisotropic Raman and polarization\u2010resolved SHG responses. The BP nanowires show remarkable environmental stability over 12 months and competitive photodetector performance, with a responsivity of 5.2 \u00d7 10\n                    <jats:sup>4<\/jats:sup>\n                    A\/W and detectivity exceeding 6.4 \u00d7 10\n                    <jats:sup>11<\/jats:sup>\n                    Jones under 595\u00a0nm illumination. The device also shows good ambient\u2010storage stability and flexible\u2010substrate compatibility. Integration with MoS\n                    <jats:sub>2<\/jats:sub>\n                    amplifies polarization discrimination, achieving an anisotropy ratio of 2.87 at 532\u00a0nm, surpassing previously reported low\u2010dimensional systems. This work establishes strain\u2013phonon coupling\u2010mediated polarization control as a new paradigm for BP\u2010based optoelectronic and photonic platforms.\n                  <\/jats:p>","DOI":"10.1002\/anie.3135016","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T09:40:47Z","timestamp":1784540447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Strain\u2010Tunable Phonon Coupling and Polarization Optoelectronics in Supersaturation\u2010Grown Boron Phosphide Nanowires"],"prefix":"10.1002","volume":"65","author":[{"given":"Chuang","family":"Hou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Mechanics and Control for Aerospace Structures Key Laboratory of Intelligent Nano Materials and Devices of Ministry of Education Nanjing University of Aeronautics and Astronautics  Nanjing China"},{"name":"Research Center for Advanced Science and Technology The University of Tokyo  Tokyo Japan"},{"name":"Institute of Industrial Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qilong","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Mechanics and Control for Aerospace Structures Key Laboratory of Intelligent Nano Materials and Devices of Ministry of Education Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Industrial Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiamin","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Mechanics and Control for Aerospace Structures Key Laboratory of Intelligent Nano Materials and Devices of Ministry of Education Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5531-6510","authenticated-orcid":false,"given":"Hirohiko","family":"Fukagawa","sequence":"additional","affiliation":[{"name":"Center For Frontier Science Chiba University  Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manato","family":"Tateno","sequence":"additional","affiliation":[{"name":"Graduate School of Science and Engineering Chiba University  Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Mechanics and Control for Aerospace Structures Key Laboratory of Intelligent Nano Materials and Devices of Ministry of Education Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masahiro","family":"Nomura","sequence":"additional","affiliation":[{"name":"Institute of Industrial Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5978-2778","authenticated-orcid":false,"given":"Naoji","family":"Matsuhisa","sequence":"additional","affiliation":[{"name":"Research Center for Advanced Science and Technology The University of Tokyo  Tokyo Japan"},{"name":"Institute of Industrial Science The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9416-3753","authenticated-orcid":false,"given":"Guoan","family":"Tai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Mechanics and Control for Aerospace Structures Key Laboratory of Intelligent Nano Materials and Devices of Ministry of Education Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,20]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c01543"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377\u2010025\u201001744\u2010x"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2015.71"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7991"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2017.33"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201804733"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05730"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c09598"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2025.111859"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202517389"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.08.041"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.101.035302"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.7b03437"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201805116"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0267226"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano15090654"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b17204"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.3c00454"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501833"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214533"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/1791075a0"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.4.282"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1753975"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20100248(75)90105\u20100"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1747055"},{"key":"e_1_2_8_27_1","volume-title":"Nucleation in Condensed Matter: Applications in Materials and Biology","author":"Kelton K.","year":"2010"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2022.05.022"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00282B"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adz4766"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn503893j"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202006774"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c08892"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41377\u2010024\u201001680\u20102"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310427"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2021.160195"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c01977"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b00906"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b03119"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010025\u201001759\u20101"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.164753"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201504135"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c09912"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313721"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209995"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202410163"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201701342"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201903580"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201906958"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201906040"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4249"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c04455"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202314743"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c05283"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010019\u20102364\u20101"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c03673"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202203003"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201002093\u2010z"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c09593"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsphotonics.8b00318"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201900314"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201600069"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202101017"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c19526"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201703286"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2025.162428"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2021.151035"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201804541"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202314838"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202104787"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c01303"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c09674"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA01223A"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202008078"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.8b06629"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201900411"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201900622"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202111673"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202202658"},{"key":"e_1_2_8_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c12332"},{"key":"e_1_2_8_81_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c00273"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.3135016","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.3135016","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.3135016","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T14:41:05Z","timestamp":1790001665000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.3135016"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,20]]},"references-count":80,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2026,9,21]]}},"alternative-id":["10.1002\/anie.3135016"],"URL":"https:\/\/doi.org\/10.1002\/anie.3135016","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,20]]},"assertion":[{"value":"2026-05-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-08","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-20","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e3135016"}}