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In this study, a unique organic polymer (Ni\u2010HAT CN), rich in lithiophilic sites and cationic groups, is designed as a protective layer for lithium metal anodes (LMAs) to enable uniform lithium deposition and enhance Li\n                    <jats:sup>+<\/jats:sup>\n                    flux. On one hand, the positively charged Ni\n                    <jats:sup>2+<\/jats:sup>\n                    sites in the polymer modify the electronic structure and provide robust electrostatic shielding to suppress adverse side reactions. On the other hand, the dense lithiophilic sites (C\u2550N, C\u2261N, etc.) in HAT CN facilitate Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion and accelerate the desolvation process of Li\n                    <jats:sup>+<\/jats:sup>\n                    . Furthermore, the in\u2010depth working mechanisms behind these effects are revealed through a variety of in situ\/ex situ characterizations and theoretical calculations. As a result, the Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number of the Ni\u2010HAT CN\u2010protected battery increases to 0.76, and it exhibits stable cycling for over 3000\u00a0h (3\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ). The full cell maintains high capacity after 900 stable cycles at 1 C, with an average ultra\u2010low degradation rate of just 0.047% per cycle. This work offers a novel strategy for stabilizing LMAs by uniquely combining electrostatic field construction with the regulation of solvation structures.\n                  <\/jats:p>","DOI":"10.1002\/anie.3142983","type":"journal-article","created":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T07:19:39Z","timestamp":1775891979000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Cationic Organic Polymers With Electrostatic Shielding Effect and Lithiophilic Sites for Dendrite\u2010Free Lithium Metal Batteries"],"prefix":"10.1002","volume":"65","author":[{"given":"Songling","family":"Wu","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering School of Environmental and Chemical Engineering Shanghai University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beisha","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Chemical 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