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Although this transformation is well established with ruthenium\u2010, rhodium\u2010, and iridium\u2010based catalysts, analogous reactions catalyzed by earth\u2010abundant metals remain limited, particularly for acyclic olefins. Here we report a manganese catalytic system that enables highly enantioselective reduction of both cyclic and acyclic olefins, delivering diverse chiral products in up to 99% yield and &gt;99%\n                    <jats:italic>ee<\/jats:italic>\n                    . Density functional theory (DFT) studies indicate that the reaction proceeds predominantly through a concerted hydrogen\u2010transfer pathway involving a six\u2010membered transition state. These results expand the scope of manganese\u2010catalyzed asymmetric olefin transfer hydrogenation and provide mechanistic insight into hydrogen transfer by base\u2010metal catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.3186961","type":"journal-article","created":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T18:39:20Z","timestamp":1785263960000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Manganese\u2010Catalyzed Asymmetric Transfer Hydrogenation of Polarized Olefins via a Collaborative Hydrogen Transfer Process"],"prefix":"10.1002","volume":"65","author":[{"given":"Chao","family":"Xiong","sequence":"first","affiliation":[{"name":"Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education College of Pharmaceutical Sciences Zhejiang University of Technology  Hangzhou P. R. 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