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Nevertheless, molecular engineering strategies for achieving efficient red\u2010light heterogeneous photocatalysts remain scarce and pose significant challenges. Herein, this work designed and synthesized two novel isostructural metal\u2013organic frameworks (MOFs, denoted as NHEt\u2010cNDI\u2010Cu\n                    <jats:sub>3<\/jats:sub>\n                    and SEt\u2010cNDI\u2010Cu\n                    <jats:sub>3<\/jats:sub>\n                    ) based on core\u2010substituted naphthalenediimide (cNDI) derived dyes. The two MOFs exhibited comparative high surface area and decent water\/chemical stability. Intriguingly, their broad and intense light absorption, which is intrinsically inherited from their constituent cNDI ligands, bestowed them with great promise in long\u2010wavelength light photocatalysis. Especially, NHEt\u2010cNDI\u2010Cu\n                    <jats:sub>3<\/jats:sub>\n                    was found to be quite prominent in photocatalyzed sulfide oxidations and oxidative coupling of benzylamine under red\u2010light irradiation. In contrast, the performance of its analogue, SEt\u2010cNDI\u2010Cu\n                    <jats:sub>3,<\/jats:sub>\n                    was five times lower, although their photocatalytic activity was very close under blue\u2010light excitation. The mechanistic study further elucidated that the LUMO of cNDI\u2010based MOFs governed the photocatalytic reactivity, which furnished a new platform for molecular engineering design of long\u2010wavelength photocatalysts and subsequently boosted sustainable chemistry.\n                  <\/jats:p>","DOI":"10.1002\/anie.3220283","type":"journal-article","created":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T11:09:57Z","timestamp":1783508997000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Modular Core\u2010Substituted Naphthalenediimide\u2010Based Metal\u2013Organic Frameworks for Red\u2010Light\u2010Driven Photocatalysis"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhiruo","family":"Tang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, College of Materials Science and Engineering Fuzhou University  Fuzhou Fujian P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Wang","sequence":"additional","affiliation":[{"name":"Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and Science  Xiangyang Hubei P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3181-0327","authenticated-orcid":false,"given":"Zhiyong","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, College of Materials Science and Engineering Fuzhou University  Fuzhou Fujian P. R. 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