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The hybrid photoenzyme catalyst establishes localized internal electric fields (IEF) between cyt\n                    <jats:italic>c<\/jats:italic>\n                    and CN that promote exciton dissociation, and creates polarized active sites on cyt\n                    <jats:italic>c<\/jats:italic>\n                    that preferentially adsorb O\n                    <jats:sub>2<\/jats:sub>\n                    , and activate O\n                    <jats:sub>2<\/jats:sub>\n                    to active peroxides (\u2022O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and *O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ) via an electron transfer pathway with inhibiting\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    formation. The one\u2010step NO oxidation to NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    is boosted over cyt\n                    <jats:italic>c<\/jats:italic>\n                    \/CN, showing exceptional 97.4% NO conversion with ultralow NO\n                    <jats:sub>2<\/jats:sub>\n                    selectivity (1.5%, 6.5 ppb) and long\u2010term stability (98.1% after 300\u00a0min) at a weight hourly space velocity (WHSV) of 850 L g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    across wide humidity ranges. The undesirable NO\n                    <jats:sub>2<\/jats:sub>\n                    generation is significantly lower than that of bare CN (17.0%, 104.7 ppb) and reported catalysts. The catalyst exhibits high activity in direct NO\n                    <jats:sub>2<\/jats:sub>\n                    removal (92.9%) and rapidly reduces NO levels to below the safe concentration (52 ppb) in a simulated environment chamber.\n                  <\/jats:p>","DOI":"10.1002\/anie.3296119","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T18:03:30Z","timestamp":1772993010000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Suppression of NO\n                    <sub>2<\/sub>\n                    Generation During One\u2010Step Deep Oxidation of NO at a Semi\u2010Artificial Photoenzyme Based on Cytochrome\n                    <i>c<\/i>"],"prefix":"10.1002","volume":"65","author":[{"given":"Jing","family":"Wang","sequence":"first","affiliation":[{"name":"Guangdong Key Laboratory of Environmental Pollution and Health College of Environment and Climate Jinan University  Guangzhou Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingling","family":"Yang","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Environmental Pollution and Health College of Environment and Climate Jinan University  Guangzhou Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jialin","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Environmental Pollution and Health College of Environment and Climate Jinan University  Guangzhou Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianle","family":"Cai","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Environmental Pollution and Health College of Environment and Climate Jinan University  Guangzhou Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5926-5383","authenticated-orcid":false,"given":"Mingshan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Guangdong Key Laboratory of Environmental Pollution and Health College of Environment and Climate Jinan University  Guangzhou Guangdong P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,23]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057861\u2010z"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002337"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056963\u2010y"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504499"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2023.103498"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b00986"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010019\u20100356\u20100"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.4c08326"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2024.110086"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202410902"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CY00674G"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c03769"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b01287"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c00622"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c05545"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09727"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202420080"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202501291"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002241"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.126228"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124163"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2024.05.002"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2426207122"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202203519"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422940"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319741"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c06171"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09263"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02084"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010022\u201001010\u20102"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43247\u2010025\u201002062\u20101"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2025.125170"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/nrm2434"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903427"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201704797"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemgeo.2024.122276"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201041522\u20100"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502430"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412194"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914949"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.123690"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/bi602523a"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2024.130402"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201378"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2022.01.025"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/es502290f"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0207053"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202417390"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201053482\u20100"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122276"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.109271"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2024.105578"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02090"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121829"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp308468j"},{"key"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