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Herein, we report a novel strategy for diazo transfer utilizing nitrous oxide (N\n                    <jats:sub>2<\/jats:sub>\n                    O) fixation at a phosphorus ylide. This method enables the efficient synthesis of valuable organic building blocks under mild, hydrazine\u2010free conditions. The one\u2010pot approach provides a safer and more practical route to diazo compounds, which can be trapped directly. This facile pathway gives access to a broad range of dinitrogen\u2010containing compounds, including 1,2,3\u2010triazolo heterocycles and (macrocyclic) aldazines. We additionally disclose a new phthalazine heterocycle synthesis utilizing bis\u2010P\u2010ylides and N\n                    <jats:sub>2<\/jats:sub>\n                    O. Both intra\u2010 and intermolecular trapping are investigated, which establishes N\n                    <jats:sub>2<\/jats:sub>\n                    O fixation as a powerful tool in synthetic methodology.\n                  <\/jats:p>","DOI":"10.1002\/anie.3352042","type":"journal-article","created":{"date-parts":[[2026,4,20]],"date-time":"2026-04-20T06:49:59Z","timestamp":1776667799000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides"],"prefix":"10.1002","volume":"65","author":[{"given":"Jhen\u2010Kuei","family":"Yu","sequence":"first","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan Niclas","family":"Ludwig","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische 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